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- W2037807790 abstract "Polarization modulation infrared spectroscopy using the Kretschmann ATR geometry has been applied to the in-situ observation of tetracyanoethylene (TCNE) anions generated electrochemically on a gold electrode in contact with an acetonitrile solution. Besides the electrode potential-independent band at 2252 cm−1 due to the CN stretching vibration of acetonitrile, a fairly strong band was observed at ca. 2170 cm−1 at a potential of −1.6 V (vs. a Ag/10−2 M Ag+ electrode). Upon a positive shift of potential, this band shifted to higher wavenumbers and decreased in intensity. At −1.2 V, a new band appeared at around 2110 cm−1 and shifted to higher wavenumbers when the potential was made more positive. On the basis of the potential dependence and peak frequencies, the 2170 and 2110 cm−1 bands are attributed to the CN stretching vibrations of TCNE2− and TCNE.− adsorbed on the Au electrode, respectively. The orientations of these species with respect to the surface are discussed on the basis of the surface selection rule." @default.
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- W2037807790 date "1990-08-01" @default.
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- W2037807790 title "Polarization modulation IR spectroscopic study of electrochemically generated species from TCNE at a gold electrode in the Kretschmann ATR geometry" @default.
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- W2037807790 doi "https://doi.org/10.1016/0022-0728(90)87204-w" @default.
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