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- W2037843971 abstract "Hydrodynamic and cyclic voltammograms were recorded in solutions of [Mo2Fe6S8(SR)9]3− (where R = p-C6H4Cl, C6H5, p-C6H4CH3, and C2CH5 and [Mo2Fe6S8(OCH3)3(SC6H5)6] 3− clusters. The solvent was dimethylformamide and the supporting electrolyte 0.1 M tetrabutylammonium perchlorate. Rotation rates between 400 and 10,000 rpm were employed for the hydrodynamic experiments, while scan rates between 0.050 and 100 V s−1 were used for the cyclic experiments. The experimental results indicate that the compounds are electroreducible and undergo two successive one-electron transfer steps. The corresponding standard heterogeneous electrochemical rate constants were k°1 ≈ k°2 ≈ 2 × 10−2 cm s−1." @default.
- W2037843971 created "2016-06-24" @default.
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- W2037843971 date "1986-03-01" @default.
- W2037843971 modified "2023-09-26" @default.
- W2037843971 title "Electroreactivity of [Mo2Fe6S8(SR)9]3− double cubane cluster complexes" @default.
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- W2037843971 doi "https://doi.org/10.1016/0022-0728(86)90055-0" @default.
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