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- W2037845916 abstract "Molar excess enthalpies at 303.15 K and atmospheric pressure are reported for 30 binary liquid mixtures of 1-iodoalkanes (iodomethane, iodoethane, 1-iodopropane, 1-iodobutane, 1-iodopentane, 1-iodohexane, 1-iodoheptane, 1-iodooctane, 1-iodododecane and 1-iodohexadecane) + n-alkanes (hexane, dodecane and hexadecane). These experimental results along with literature data on liquidvapour equilibria (excess molar Gibbs energies) and activity coefficients at infinite dilution are interpreted in terms of the DISQUAC group contribution model. The quasichemical interchange energies are the same for the whole series. The dispersive interchange energies of iodoethane and of all the higher 1-iodoalkanes are constant, but larger than for iodomethane. In general, the model reproduces the experimental data within the limits of errors. Larger discrepancies between the calculated and the experimental excess enthalpies are observed in mixtures of long-chain 1-iodoalkanes+short-chain n-alkanes. These may be attributed to conformational changes occurring in the long-chain 1-iodoalkane on mixing with the short-chain n-alkane. In contrast, it appears that 1-iodoalkanes do not significantly perturb the conformational equilibrium (or orientational order) in long-chain n-alkanes." @default.
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- W2037845916 date "1987-01-01" @default.
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- W2037845916 title "Excess enthalpies of 1-iodoalkane + n-alkane mixtures. Measurement and analysis in terms of group contributions (DISQUAC)" @default.
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- W2037845916 doi "https://doi.org/10.1016/0378-3812(87)90001-x" @default.
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