FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2037862127> ?p ?o ?g. }

• W2037862127 abstract "The binding modes of the [Ru(II)(1,10-phenanthroline)(L(1)L(2)) dipyrido[3,2-a:2',3'-c]phenazine](2+) {[Ru(phen)(py) Cl dppz](+) (L(1)=Cl, L(2)=pyridine) and ([Ru(phen)(py)(2)dppz](2+) (L(1)=L(2)=pyridine)} to native DNA is compared to that of the [Ru(II)(1,10-phenanthroline)(2)dipyrido[3,2-a:2',3'-c]phenazine](2+) complex ([Ru(phen)(2)dppz](2+)) by various spectroscopic and hydrodynamic methods including electric absorption, linear dichroism (LD), fluorescence spectroscopy, and viscometric titration. All measured properties, including red-shift and hypochromism in the dppz absorption band, nearly perpendicular molecular plane of the dppz ligand with respect to the local DNA helix axis, prohibition of the ethidium binding, the light switch effect and binding stoichiometry, increase in the viscosity upon binding to DNA, increase in the melting temperature are in agreement with classical intercalation of dppz ligand of the [Ru(phen)(2)dppz](2+) complex, in which both phenanthroline ligand anchored to the DNA phosphate groups by electrostatic interaction. [Ru(phen)(py)(2) dppz](2+) and [Ru(phen)(py) Cl dppz](+) complexes had one of the phenanthroline ligand replaced by either two pyridine ligands or one pyridine plus a chlorine ion. They exhibited similar protection from water molecules, interaction with DNA bases, and occupying site that is common with ethidium. The dppz ligand of these two Ru(II) complex were greatly tilted relative to the DNA helix axis, suggesting that the dppz ligand resides inside the DNA and is not perpendicular relative to the DNA helix axis. These observation suggest that anchoring the [Ru(phen)(2)dppz](2+)complex by both phenanthroline is essential for the dppz ligand to be classically intercalated between DNA base-pairs." @default.
• W2037862127 created "2016-06-24" @default.
• W2037862127 creator A5000799004 @default.
• W2037862127 creator A5036391545 @default.
• W2037862127 creator A5045047102 @default.
• W2037862127 creator A5079063224 @default.
• W2037862127 date "2011-09-01" @default.
• W2037862127 modified "2023-09-25" @default.
• W2037862127 title "The relationship between the structures of periphery ligands and the DNA binding mode of [Ru(II)(1,10-phenanthroline)(L1L2)dipyrido[3,2-a:2′,3′-c]phenazine]n+ (L1=Cl or pyridine and L2=pyridine, n=1,2)" @default.
• W2037862127 cites W1535196470 @default.
• W2037862127 cites W1968330562 @default.
• W2037862127 cites W1983777608 @default.
• W2037862127 cites W2005252051 @default.
• W2037862127 cites W2008803918 @default.
• W2037862127 cites W2019809374 @default.
• W2037862127 cites W2021279342 @default.
• W2037862127 cites W2024613503 @default.
• W2037862127 cites W2027537762 @default.
• W2037862127 cites W2027714893 @default.
• W2037862127 cites W2029718059 @default.
• W2037862127 cites W2056902463 @default.
• W2037862127 cites W2058519136 @default.
• W2037862127 cites W2059416161 @default.
• W2037862127 cites W2060335449 @default.
• W2037862127 cites W2061335212 @default.
• W2037862127 cites W2065207842 @default.
• W2037862127 cites W2065539815 @default.
• W2037862127 cites W2070278984 @default.
• W2037862127 cites W2073126970 @default.
• W2037862127 cites W2076223637 @default.
• W2037862127 cites W2090367744 @default.
• W2037862127 cites W2096100606 @default.
• W2037862127 cites W2120939781 @default.
• W2037862127 cites W2142604104 @default.
• W2037862127 cites W2155143705 @default.
• W2037862127 cites W2158586659 @default.
• W2037862127 cites W4235568222 @default.
• W2037862127 doi "https://doi.org/10.1016/j.bpc.2011.04.014" @default.
• W2037862127 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21601346" @default.
• W2037862127 hasPublicationYear "2011" @default.
• W2037862127 type Work @default.
• W2037862127 sameAs 2037862127 @default.
• W2037862127 citedByCount "10" @default.
• W2037862127 countsByYear W20378621272012 @default.
• W2037862127 countsByYear W20378621272013 @default.
• W2037862127 countsByYear W20378621272014 @default.
• W2037862127 countsByYear W20378621272017 @default.
• W2037862127 countsByYear W20378621272018 @default.
• W2037862127 countsByYear W20378621272021 @default.
• W2037862127 crossrefType "journal-article" @default.
• W2037862127 hasAuthorship W2037862127A5000799004 @default.
• W2037862127 hasAuthorship W2037862127A5036391545 @default.
• W2037862127 hasAuthorship W2037862127A5045047102 @default.
• W2037862127 hasAuthorship W2037862127A5079063224 @default.
• W2037862127 hasConcept C116569031 @default.
• W2037862127 hasConcept C133571119 @default.
• W2037862127 hasConcept C137824038 @default.
• W2037862127 hasConcept C155647269 @default.
• W2037862127 hasConcept C170493617 @default.
• W2037862127 hasConcept C179104552 @default.
• W2037862127 hasConcept C185592680 @default.
• W2037862127 hasConcept C2777660389 @default.
• W2037862127 hasConcept C2778370995 @default.
• W2037862127 hasConcept C2779485729 @default.
• W2037862127 hasConcept C55493867 @default.
• W2037862127 hasConcept C71240020 @default.
• W2037862127 hasConcept C8010536 @default.
• W2037862127 hasConceptScore W2037862127C116569031 @default.
• W2037862127 hasConceptScore W2037862127C133571119 @default.
• W2037862127 hasConceptScore W2037862127C137824038 @default.
• W2037862127 hasConceptScore W2037862127C155647269 @default.
• W2037862127 hasConceptScore W2037862127C170493617 @default.
• W2037862127 hasConceptScore W2037862127C179104552 @default.
• W2037862127 hasConceptScore W2037862127C185592680 @default.
• W2037862127 hasConceptScore W2037862127C2777660389 @default.
• W2037862127 hasConceptScore W2037862127C2778370995 @default.
• W2037862127 hasConceptScore W2037862127C2779485729 @default.
• W2037862127 hasConceptScore W2037862127C55493867 @default.
• W2037862127 hasConceptScore W2037862127C71240020 @default.
• W2037862127 hasConceptScore W2037862127C8010536 @default.
• W2037862127 hasLocation W20378621271 @default.
• W2037862127 hasLocation W20378621272 @default.
• W2037862127 hasOpenAccess W2037862127 @default.
• W2037862127 hasPrimaryLocation W20378621271 @default.
• W2037862127 hasRelatedWork W1965979424 @default.
• W2037862127 hasRelatedWork W1988598189 @default.
• W2037862127 hasRelatedWork W1990845975 @default.
• W2037862127 hasRelatedWork W2009252771 @default.
• W2037862127 hasRelatedWork W2032427906 @default.
• W2037862127 hasRelatedWork W2039044036 @default.
• W2037862127 hasRelatedWork W2042062103 @default.
• W2037862127 hasRelatedWork W2043561905 @default.
• W2037862127 hasRelatedWork W2061533585 @default.
• W2037862127 hasRelatedWork W2074295848 @default.
• W2037862127 hasRelatedWork W2088328928 @default.
• W2037862127 hasRelatedWork W2117600811 @default.
• W2037862127 hasRelatedWork W2158447689 @default.
• W2037862127 hasRelatedWork W2182088910 @default.
• W2037862127 hasRelatedWork W2188646636 @default.
• W2037862127 hasRelatedWork W2289764551 @default.

• next