FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2037893105> ?p ?o ?g. }

• W2037893105 endingPage "179" @default.
• W2037893105 startingPage "164" @default.
• W2037893105 abstract "Abstract Heteronuclear macrocyclic complex of iron and copper, FeCuL(NO3)24H2O [L = (CH3C6H2CH2O(CH2)3N)2] was synthesized and characterized using CHN and X-ray crystallography. A general scheme for bonding the complexes ionically on acidified montmorillonite clay was evolved and the thermogravimetric analysis of the final catalyst showed that it was stable up to 400 °C. The increased thermal and chemical stability of the complex bonded to the clay has been explained through enhanced interactive energy between them and its higher catalytic efficiency has been demonstrated through the following reaction. The oxidation of cyclohexane in presence of this catalyst using molecular oxygen in the absence of intiators, promoters and coreactants was studied in the temperature range of 150–210 °C. All commercial catalyst reported are known to form cyclohexanol and cyclohexanone in about equimolar ratio, but with our catalyst, cyclohexanone along with small amount of uncharacterized waste products (D) were formed and the selectivity of the former decreases (due to the formation of large amount of D) with increase in temperature. The experimental data were analyzed against different kinetic scheme available in literature and the rate constants of the best scheme were determined using Genetic Algorithm. From the experiments carried out at different temperatures and pressures, we found that for every rate constant, an Arrhenius type relation (independent of reactor pressure) could be established." @default.
• W2037893105 created "2016-06-24" @default.
• W2037893105 creator A5015665002 @default.
• W2037893105 creator A5019120028 @default.
• W2037893105 date "2007-06-01" @default.
• W2037893105 modified "2023-09-27" @default.
• W2037893105 title "Oxidation of cyclohexane with molecular oxygen in presence of characterized macrocyclic heteronuclear FeCu complex catalyst ionically bonded to zirconium pillared montmorillonite clay" @default.
• W2037893105 cites W1964993120 @default.
• W2037893105 cites W1974677331 @default.
• W2037893105 cites W1982962259 @default.
• W2037893105 cites W1982975139 @default.
• W2037893105 cites W1984608244 @default.
• W2037893105 cites W1987946870 @default.
• W2037893105 cites W1995435511 @default.
• W2037893105 cites W2002969840 @default.
• W2037893105 cites W2005074617 @default.
• W2037893105 cites W2006687227 @default.
• W2037893105 cites W2007709937 @default.
• W2037893105 cites W2011190695 @default.
• W2037893105 cites W2012163683 @default.
• W2037893105 cites W2016564597 @default.
• W2037893105 cites W2021055677 @default.
• W2037893105 cites W2022355866 @default.
• W2037893105 cites W2022532142 @default.
• W2037893105 cites W2030897157 @default.
• W2037893105 cites W2033539176 @default.
• W2037893105 cites W2034911700 @default.
• W2037893105 cites W2037296621 @default.
• W2037893105 cites W2038792007 @default.
• W2037893105 cites W2041433990 @default.
• W2037893105 cites W2047799324 @default.
• W2037893105 cites W2056958269 @default.
• W2037893105 cites W2057193268 @default.
• W2037893105 cites W2062187215 @default.
• W2037893105 cites W2065716489 @default.
• W2037893105 cites W2066512076 @default.
• W2037893105 cites W2070414849 @default.
• W2037893105 cites W2073668407 @default.
• W2037893105 cites W2075338983 @default.
• W2037893105 cites W2076840408 @default.
• W2037893105 cites W2076872835 @default.
• W2037893105 cites W2079646096 @default.
• W2037893105 cites W2080293799 @default.
• W2037893105 cites W2088306165 @default.
• W2037893105 cites W2089123627 @default.
• W2037893105 cites W2093551790 @default.
• W2037893105 cites W2103606262 @default.
• W2037893105 cites W2104342355 @default.
• W2037893105 cites W2144486764 @default.
• W2037893105 cites W2316960789 @default.
• W2037893105 cites W4232890111 @default.
• W2037893105 doi "https://doi.org/10.1016/j.molcata.2007.02.045" @default.
• W2037893105 hasPublicationYear "2007" @default.
• W2037893105 type Work @default.
• W2037893105 sameAs 2037893105 @default.
• W2037893105 citedByCount "28" @default.
• W2037893105 countsByYear W20378931052012 @default.
• W2037893105 countsByYear W20378931052013 @default.
• W2037893105 countsByYear W20378931052014 @default.
• W2037893105 countsByYear W20378931052015 @default.
• W2037893105 countsByYear W20378931052016 @default.
• W2037893105 countsByYear W20378931052017 @default.
• W2037893105 countsByYear W20378931052018 @default.
• W2037893105 countsByYear W20378931052019 @default.
• W2037893105 countsByYear W20378931052020 @default.
• W2037893105 countsByYear W20378931052022 @default.
• W2037893105 countsByYear W20378931052023 @default.
• W2037893105 crossrefType "journal-article" @default.
• W2037893105 hasAuthorship W2037893105A5015665002 @default.
• W2037893105 hasAuthorship W2037893105A5019120028 @default.
• W2037893105 hasConcept C161790260 @default.
• W2037893105 hasConcept C178790620 @default.
• W2037893105 hasConcept C179104552 @default.
• W2037893105 hasConcept C185592680 @default.
• W2037893105 hasConcept C188027245 @default.
• W2037893105 hasConcept C192562407 @default.
• W2037893105 hasConcept C2777515222 @default.
• W2037893105 hasConcept C2778237882 @default.
• W2037893105 hasConcept C32909587 @default.
• W2037893105 hasConcept C534791751 @default.
• W2037893105 hasConcept C540031477 @default.
• W2037893105 hasConcept C92381491 @default.
• W2037893105 hasConceptScore W2037893105C161790260 @default.
• W2037893105 hasConceptScore W2037893105C178790620 @default.
• W2037893105 hasConceptScore W2037893105C179104552 @default.
• W2037893105 hasConceptScore W2037893105C185592680 @default.
• W2037893105 hasConceptScore W2037893105C188027245 @default.
• W2037893105 hasConceptScore W2037893105C192562407 @default.
• W2037893105 hasConceptScore W2037893105C2777515222 @default.
• W2037893105 hasConceptScore W2037893105C2778237882 @default.
• W2037893105 hasConceptScore W2037893105C32909587 @default.
• W2037893105 hasConceptScore W2037893105C534791751 @default.
• W2037893105 hasConceptScore W2037893105C540031477 @default.
• W2037893105 hasConceptScore W2037893105C92381491 @default.
• W2037893105 hasIssue "1-2" @default.
• W2037893105 hasLocation W20378931051 @default.
• W2037893105 hasOpenAccess W2037893105 @default.
• W2037893105 hasPrimaryLocation W20378931051 @default.

• next