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- W2037893920 abstract "Abstract Pocahontas No. 3 coal was extracted with CS2, n-hexane, benzene, methanol, acetone, and acetone/CS2 (1:1 vol/vol) mixed solvent sequentially. The resulting six extracts were analyzed with gas chromatography/mass spectrometer (GC/MS). Hexathiane, octathiocane, 23 sulfur-containing organic species, and 21 nitrogen-containing organic species were detected in the extracts. Sulfur-containing organic species detected in the extracts include dialkyl- and disulfides, dimexano, dibenzothiophene, benzonaphthothiophene, and their methyl-derivatives, among which dimexano and dixanthogen were seldom reported in any sediments. Methanol is effective for extracting sulfur-containing organic species without aromatic ring. Most of the nitrogen-containing organic species detected in the extracts are acridinone, carbazole and their methyl-derivatives, benzocarbazoles, amines, phenanthridinone, and piperidinone. The species number of nitrogen-containing organic compounds detected in the extracts increased with the increase in solvent polarity. Different from those reported previously, N and O atoms often coexist in the same compounds in the present study." @default.
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- W2037893920 date "2010-04-15" @default.
- W2037893920 modified "2023-10-05" @default.
- W2037893920 title "Identification of Sulfur- and Nitrogen-containing Organic Species in the Extracts from Pocahontas No. 3 Coal" @default.
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- W2037893920 doi "https://doi.org/10.1080/15567030802612077" @default.
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