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- W2037928008 endingPage "4340" @default.
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- W2037928008 abstract "The dependence of the chemiluminescence cross section on initial spin-orbit level has been measured for the reaction of metastable Ca(4s4p 3P0J) with Cl2, CH3Br, CH2Br2, CH2=CHCH2Br, and C6H5CH2Br, using an optical pumping state selection technique. Optical pumping depletion was also used to determine what fraction of the chemiluminescence was due to the second metastable Ca(4s3d 1D) level present in the incident atomic beam. Chemiluminescence cross sections for both the 3P0 and 1D reactions were separately determined; total attenuation and intramultiplet mixing cross sections were also estimated. The Ca(3P0) spin-orbit dependence for the chemiluminescence channel in all the reactions studied was substantial and of similar magnitude, with an order of reactivity J=2>J=1>J=0. This spin-orbit selectivity is related to differences in the evolution of the asymptotic spin-orbit states onto the various electrostatic surfaces at smaller separations. It is remarkable that this selectivity persists with polyatomic reagents." @default.
- W2037928008 created "2016-06-24" @default.
- W2037928008 creator A5021389952 @default.
- W2037928008 creator A5052062252 @default.
- W2037928008 creator A5063810131 @default.
- W2037928008 date "1986-04-15" @default.
- W2037928008 modified "2023-09-27" @default.
- W2037928008 title "Dependence of the chemiluminescence cross section on spin-orbit state for the reaction of Ca(3<i>P</i>0<i>J</i>) with alkyl bromides" @default.
- W2037928008 cites W1570740345 @default.
- W2037928008 cites W1602070516 @default.
- W2037928008 cites W1969794839 @default.
- W2037928008 cites W1970856718 @default.
- W2037928008 cites W1971023972 @default.
- W2037928008 cites W1974245596 @default.
- W2037928008 cites W1987144722 @default.
- W2037928008 cites W1989127501 @default.
- W2037928008 cites W1989540023 @default.
- W2037928008 cites W1991173096 @default.
- W2037928008 cites W1991497897 @default.
- W2037928008 cites W1992389782 @default.
- W2037928008 cites W1995012683 @default.
- W2037928008 cites W1995035085 @default.
- W2037928008 cites W1997065530 @default.
- W2037928008 cites W1997529257 @default.
- W2037928008 cites W2002197654 @default.
- W2037928008 cites W2003309913 @default.
- W2037928008 cites W2004017947 @default.
- W2037928008 cites W2004385970 @default.
- W2037928008 cites W2004632232 @default.
- W2037928008 cites W2012844069 @default.
- W2037928008 cites W2015498199 @default.
- W2037928008 cites W2017124534 @default.
- W2037928008 cites W2017414753 @default.
- W2037928008 cites W2018380099 @default.
- W2037928008 cites W2021858162 @default.
- W2037928008 cites W2022490223 @default.
- W2037928008 cites W2024065291 @default.
- W2037928008 cites W2025413877 @default.
- W2037928008 cites W2027143107 @default.
- W2037928008 cites W2030396126 @default.
- W2037928008 cites W2033921770 @default.
- W2037928008 cites W2038479854 @default.
- W2037928008 cites W2038802922 @default.
- W2037928008 cites W2042520755 @default.
- W2037928008 cites W2044362167 @default.
- W2037928008 cites W2046624935 @default.
- W2037928008 cites W2051013298 @default.
- W2037928008 cites W2054428122 @default.
- W2037928008 cites W2055183132 @default.
- W2037928008 cites W2055550773 @default.
- W2037928008 cites W2058845207 @default.
- W2037928008 cites W2059519844 @default.
- W2037928008 cites W2060729124 @default.
- W2037928008 cites W2061770447 @default.
- W2037928008 cites W2064040536 @default.
- W2037928008 cites W2064981651 @default.
- W2037928008 cites W2071265669 @default.
- W2037928008 cites W2072334502 @default.
- W2037928008 cites W2073954279 @default.
- W2037928008 cites W2075983807 @default.
- W2037928008 cites W2077597057 @default.
- W2037928008 cites W2078930868 @default.
- W2037928008 cites W2079104460 @default.
- W2037928008 cites W2079368756 @default.
- W2037928008 cites W2083606729 @default.
- W2037928008 cites W2084595304 @default.
- W2037928008 cites W2084741270 @default.
- W2037928008 cites W2084998435 @default.
- W2037928008 cites W2085366533 @default.
- W2037928008 cites W2086038518 @default.
- W2037928008 cites W2087044770 @default.
- W2037928008 cites W2087175283 @default.
- W2037928008 cites W2088062772 @default.
- W2037928008 cites W2088191341 @default.
- W2037928008 cites W2090616682 @default.
- W2037928008 cites W2092850513 @default.
- W2037928008 cites W2092979710 @default.
- W2037928008 cites W2093721495 @default.
- W2037928008 cites W2103444572 @default.
- W2037928008 cites W2108005022 @default.
- W2037928008 cites W2155395417 @default.
- W2037928008 cites W270487965 @default.
- W2037928008 cites W2916659777 @default.
- W2037928008 cites W3005167260 @default.
- W2037928008 cites W3005227153 @default.
- W2037928008 cites W332477774 @default.
- W2037928008 cites W4233262796 @default.
- W2037928008 cites W4242340867 @default.
- W2037928008 doi "https://doi.org/10.1063/1.450055" @default.
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