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- W2037963005 abstract "Enantioselective deprotonation of 4-substituted cyclohexanones (1) in the presence of excess trimethylsilyl chloride was examined using chiral bidentate lithium amides ((R)-3∼(R)-7) in THF. The solution structures of (R)-3a in THF in the presence and in the absence of lithium chloride were studied by NMR. It is concluded that the eight-membered cyclic transition state (10) offers reasonable explanation of the stereochemical course of the present reaction using (R)-3a." @default.
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- W2037963005 date "1997-01-01" @default.
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- W2037963005 title "Stereochemistry of enantioselective deprotonation of 4-substituted cyclohexanones by chiral bidentate lithium amides" @default.
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- W2037963005 doi "https://doi.org/10.1016/s0040-4039(96)02373-8" @default.
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