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- W2037982425 abstract "Abstract YbSi 2 and the derivatives Yb T x Si 2– x ( T = Cr, Fe, Co) crystallizing in the α‐ThSi 2 structure type were obtained as single crystals from reactions run in liquid indium. All silicides were investigated by single‐crystal X‐ray diffraction, I 4 1 / amd space group and the lattice constants are: a = 3.9868(6) Å and c = 13.541(3) Å for YbSi 2 , a = 4.0123(6) Å and c = 13.542(3) Å for YbCr 0.27 Si 1.73 , a = 4.0142(6) Å and c = 13.830(3) Å for YbCr 0.71 Si 1.29 , a = 4.0080(6) Å and c = 13.751(3) Å for YbFe 0.34 Si 1.66 , and a = 4.0036(6) Å, c = 13.707(3) Å for YbCo 0.21 Si 1.79 . YbSi 2 and Yb T x Si 2– x compounds are polar intermetallics with three‐dimensional Si and M ( T +Si) polyanion sub‐networks, respectively, filled with ytterbium atoms. The degree of substitution of transition metal at the silicon site is signficant and leads to changes in the average bond lengths and bond angles substantially." @default.
- W2037982425 created "2016-06-24" @default.
- W2037982425 creator A5035758112 @default.
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- W2037982425 date "2012-01-05" @default.
- W2037982425 modified "2023-10-18" @default.
- W2037982425 title "ThSi2 Type Ytterbium Disilicide and its Analogues YbTxSi2-x (T = Cr, Fe, Co)" @default.
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- W2037982425 doi "https://doi.org/10.1002/zaac.201100284" @default.
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