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- W2037992725 abstract "The kinetics of the reactions C2H5+OH(+M)→products (+M) (1) were studied at room temperature by pulse radiolysis of C2H6/H2O/SF6 mixtures. The ethyl radical decay was followed by monitoring the UV absorption signals at 205 nm. The experimentally determined value of k1 is (7.1 ± 1.0) × 1010 M−1 s−1. No pressure dependence of k1 in the pressure range 250–1000 mbar SF6 was observed. The calculated k1a,∞ value for the temperature range 200–400 K is (7.7 ± 12.0) × 1010 M−1 s−1 for the addition reaction. The low-pressure limiting rate constant for the addition reaction should not be lower than 1017 M−2 s−1 at room temperature." @default.
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- W2037992725 date "1993-06-01" @default.
- W2037992725 modified "2023-10-03" @default.
- W2037992725 title "Kinetics of the gas-phase reaction between ethyl and hydroxyl radicals" @default.
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- W2037992725 doi "https://doi.org/10.1016/0009-2614(93)89083-t" @default.
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