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- W2038004620 abstract "Abstract Crystals of the four new binary rare earth metal polyselenides LaSe 1.85 , CeSe 1.83 , NdSe 1.83 and SmSe 1.84 were obtained by flux reactions. Their two-dimensionally incommensurately modulated structures were solved from X-ray diffraction data. Structure models were established in super space group X 4/ n (– αβ 0)( βα 0)00 with modulation wave vectors q 1 = – α a * + β b * and q 2 = β a * + α b * and the centering vector (0, 0, 1/2, 1/2, 1/2). The unit cell parameters at T = 293 K are a = 4.216(1) Å and c = 17.048(2) Å for LaSe 1.85 , a = 4.178(1) Å and c = 16.942(3) Å for CeSe 1.83 , a = 4.123(1) Å and c = 16.792(2) Å for NdSe 1.83 and a = 4.080(1) Å and c = 16.672(2) Å for SmSe 1.84 ; the components of the modulation wave vectors are α = β = 0.292(1) for LaSe 1.85 and CeSe 1.83 , and α = β = 0.293(1) for NdSe 1.83 and SmSe 1.84 , respectively. The modulation originates from a site occupancy wave caused by defects in planar selenium layers coupled to a displacive modulation." @default.
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- W2038004620 date "2009-12-01" @default.
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- W2038004620 title "LaSe<sub>1.85</sub>, CeSe<sub>1.83</sub>, NdSe<sub>1.83</sub> and SmSe<sub>1.84</sub> – four new rare earth metal polyselenides with incommensurate site occupancy and displacive modulation" @default.
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- W2038004620 doi "https://doi.org/10.1524/zkri.2009.1197" @default.
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