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- W2038028861 abstract "The X-ray stimulated luminescence spectra of Ar crystals having 0.01% and 5% N2 impurities were studied at 4.2 and 77 K, in the region of the Vegard-Kaplan (A3Σ → X1ΣΣ) bands. Each band of the 5% N2/Ar system, at 4.2 K, was composed of three, almost equispaced, peaks. The fine structure was defined by a two-peak asymmetric sideband, between 25 and 180 cm−1, to the red of the N2 electronic-vibrational transition. At other impurity concentrations and crystal temperatures, different relaxation rates were found but no fine structure was observed. The whole Vegard-Kaplan band system for N2/Ar at 4.2 K was found to be shifted by (128 ± 15) cm−1, to the red of V00,. the free molecule transition. Mit Röntgenstrahleii-stimulierte Lum ineszenzspektren von Ar-Kristallen mit 0,01% und 5% N2 wurden bei 4,2 und 77 K im Gebiet der Vegard-Kaplan (A3Σ → X1Σ)-Banden untersucht. Jede der Banden im System 5% N2/Ar bei 4,2 K bestand aus drei nahezu equi-distanten Komponenten: nämlich einer Hauptbande auf Grund des Elektron-Vibrations-überganges des Stickstoffmoleküls und einer um 25 bis 180 cm−1 zum Roten verschobenen Seitenbande, die unsymmetrisch ist und aus zwei Komponenten besteht. Im Falle anderer Verunreinigungskonzentrationen und anderer Kristalltemperaturen wurden zwar unter-schiedliche Relaxationsraten gefunden, jedoch keine Feinstruktur der einzelnen Banden beobachtet. Das gesamte Vegard-Kaplan-Bandensystem für N2/Ar bei 4,2 K ist um (128 ± ± 15) cm−1 nach dem Roten hin gegen den v00-Übergang des freien N2-Moleküls verschoben." @default.
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- W2038028861 date "1975-01-01" @default.
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- W2038028861 title "Luminescence spectra of nitrogen in solid argon I. Experiment" @default.
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- W2038028861 doi "https://doi.org/10.1002/pssb.2220670117" @default.
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