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• W2038046249 endingPage "11408" @default.
• W2038046249 startingPage "11398" @default.
• W2038046249 abstract "The reactivity of the dinuclear platinum(III) derivative [(R(F))2Pt(III)(μ-PPh2)2Pt(III)(R(F))2](Pt-Pt) (R(F) = C6F5) (1) toward OH(-), N3(-), and NCO(-) was studied. The coordination of these nucleophiles to a metal center evolves with reductive coupling or reductive elimination between a bridging diphenylphosphanido group and OH(-), N3(-), and NCO(-) or C6F5 groups and formation of P-O, P-N, or P-C bonds. The addition of OH(-) to 1 evolves with a reductive coupling with the incoming ligand, formation of a P-O bond, and the synthesis of [NBu4]2[(R(F))2Pt(II)(μ-OPPh2)(μ-PPh2)Pt(II)(R(F))2] (3). The addition of N3(-) takes place through two ways: (a) formation of the P-N bond and reductive elimination of PPh2N3 yielding [NBu4]2[(R(F))2Pt(II)(μ-N3)(μ-PPh2)Pt(II)(R(F))2] (4a) and (b) formation of the P-C bond and reductive coupling with one of the C6F5 groups yielding [NBu4][(R(F))2Pt(II)(μ-N3)(μ-PPh2)Pt(II)(R(F))(PPh2R(F))] (4b). Analogous behavior was shown in the addition of NCO(-) to 1 which afforded [NBu4]2[(R(F))2Pt(II)(μ-NCO)(μ-PPh2)Pt(II)(R(F))2] (5a) and [NBu4][(R(F))2Pt(II)(μ-NCO)(μ-PPh2)Pt(II)(R(F))(PPh2R(F))] (5b). In the reaction of the trinuclear complex [(R(F))2Pt(III)(μ-PPh2)2Pt(III)(μ-PPh2)2Pt(II)(R(F))2](Pt(III)-Pt(III)) (2) with OH(-) or N3(-), the coordination of the nucleophile takes place selectively at the central platinum(III) center, and the PPh2/OH(-) or PPh2/N3(-) reductive coupling yields the trinuclear [NBu4]2[(R(F))2Pt(II)(μ-Ph2PO)(μ-PPh2)Pt(II)(μ-PPh2)2Pt(II)(R(F))2] (6) and [NBu4][(R(F))2Pt(1)(μ3-Ph2PNPPh2)(μ-PPh2)Pt(2)(μ-PPh2)Pt(3)(R(F))2](Pt(2)-Pt(3)) (7). Complex 7 is fluxional in solution, and an equilibrium consisting of Pt-Pt bond migration was ascertained by (31)P EXSY experiments." @default.
• W2038046249 created "2016-06-24" @default.
• W2038046249 creator A5002893761 @default.
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• W2038046249 creator A5051082514 @default.
• W2038046249 date "2013-09-12" @default.
• W2038046249 modified "2023-10-17" @default.
• W2038046249 title "Addition of Nucleophiles to Phosphanido Derivatives of Pt(III): Formation of P–C, P–N, and P–O Bonds" @default.
• W2038046249 cites W1964319266 @default.
• W2038046249 cites W1968619175 @default.
• W2038046249 cites W1971177699 @default.
• W2038046249 cites W1973074784 @default.
• W2038046249 cites W1974771526 @default.
• W2038046249 cites W1977041548 @default.
• W2038046249 cites W1979218012 @default.
• W2038046249 cites W1981335134 @default.
• W2038046249 cites W1982584936 @default.
• W2038046249 cites W1985355340 @default.
• W2038046249 cites W1985720552 @default.
• W2038046249 cites W1988594523 @default.
• W2038046249 cites W1991200342 @default.
• W2038046249 cites W1998689790 @default.
• W2038046249 cites W2000302945 @default.
• W2038046249 cites W2003203221 @default.
• W2038046249 cites W2004469993 @default.
• W2038046249 cites W2005390741 @default.
• W2038046249 cites W2005679105 @default.
• W2038046249 cites W2006649030 @default.
• W2038046249 cites W2006757041 @default.
• W2038046249 cites W2007571677 @default.
• W2038046249 cites W2007677790 @default.
• W2038046249 cites W2009316013 @default.
• W2038046249 cites W2009662701 @default.
• W2038046249 cites W2015056346 @default.
• W2038046249 cites W2016411575 @default.
• W2038046249 cites W2019678404 @default.
• W2038046249 cites W2021807748 @default.
• W2038046249 cites W2024424908 @default.
• W2038046249 cites W2024525101 @default.
• W2038046249 cites W2025066146 @default.
• W2038046249 cites W2026125067 @default.
• W2038046249 cites W2026215549 @default.
• W2038046249 cites W2026958349 @default.
• W2038046249 cites W2027827329 @default.
• W2038046249 cites W2028082579 @default.
• W2038046249 cites W2031236542 @default.
• W2038046249 cites W2033409314 @default.
• W2038046249 cites W2035729553 @default.
• W2038046249 cites W2037413350 @default.
• W2038046249 cites W2038599877 @default.
• W2038046249 cites W2040888967 @default.
• W2038046249 cites W2043510643 @default.
• W2038046249 cites W2047104738 @default.
• W2038046249 cites W2050836875 @default.
• W2038046249 cites W2053309831 @default.
• W2038046249 cites W2054599743 @default.
• W2038046249 cites W2054866816 @default.
• W2038046249 cites W2063419195 @default.
• W2038046249 cites W2066017043 @default.
• W2038046249 cites W2066309940 @default.
• W2038046249 cites W2067952633 @default.
• W2038046249 cites W2068162500 @default.
• W2038046249 cites W2072573552 @default.
• W2038046249 cites W2076300188 @default.
• W2038046249 cites W2077403670 @default.
• W2038046249 cites W2080502708 @default.
• W2038046249 cites W2081338240 @default.
• W2038046249 cites W2082088034 @default.
• W2038046249 cites W2083466274 @default.
• W2038046249 cites W2089849632 @default.
• W2038046249 cites W2094031837 @default.
• W2038046249 cites W2098936752 @default.
• W2038046249 cites W2105236300 @default.
• W2038046249 cites W2121237359 @default.
• W2038046249 cites W2123101018 @default.
• W2038046249 cites W2127032088 @default.
• W2038046249 cites W2129827657 @default.
• W2038046249 cites W2142809411 @default.
• W2038046249 cites W2150635455 @default.
• W2038046249 cites W2151416474 @default.
• W2038046249 cites W2155200603 @default.
• W2038046249 cites W2161312659 @default.
• W2038046249 cites W2312408380 @default.
• W2038046249 cites W2315259439 @default.
• W2038046249 cites W2324648410 @default.
• W2038046249 cites W2325979207 @default.
• W2038046249 cites W2328470955 @default.
• W2038046249 cites W2330500388 @default.
• W2038046249 cites W2330531584 @default.
• W2038046249 cites W2332207732 @default.
• W2038046249 cites W2333593271 @default.
• W2038046249 cites W2334243492 @default.
• W2038046249 cites W2334303757 @default.

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