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- W2038062512 abstract "[Mo3S7(dtc)3]dtc (dtc = S2CNEt2) reacts with one or more equivalents of TCNQ (7,7,8,8-tetracyanoquinodimethane) in CH3CN to form radical-anion salts [Mo3S7(dtc)3]2(TCNQ)2 (1) and [Mo3S7(dtc)3](TCNQ)2 (2), respectively. By an analogous method from [Mo3Se7(dtc)3]dtc the seleno complex [Mo3Se7(dtc)3](TCNQ)2 (3) was obtained. The structure of 1 was established by X-ray structural analysis. The crystals are orthorhombic, space group Pbca, a=24.388(4), b=14.043(2), c=25.224(6) Å. The structure has been solved to RF 0.049. The geometry of the [Mo3S7(dtc)3]+ cation is normal; the most interesting feature of the structure is the presence of rather short contacts between N atoms of TCNQ and S atoms of S2 ligands of the cation (the S…N distances are 2.91-2.95 Å). The TCNQ anions form centrosymmetrical dimers (the separation between the corresponding planes is 3.16 Å), so the formula of I can be written as [MO3S7(dtc)3]2(TCNQ)2." @default.
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- W2038062512 date "1992-04-01" @default.
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- W2038062512 title "Synthesis and crystal structure of [Mo3S7(S2CNEt2)3]2(TCNQ)2; salt of a radical anion and a cluster cation" @default.
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- W2038062512 doi "https://doi.org/10.1016/s0020-1693(00)82662-6" @default.
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