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- W2038063204 abstract "Catalytic reactions of the type dichloromethane → ketene and chlorobenzene → benzoic acid esters (or benzaldehyde) are possible with Pd complexes, although the turnover numbers are still small. The CCl bond in CH2C12 is even activated by [Pd(PCy3)2(dba)]/PCy3 and the CCl bond in PhCI by Pd(CH3COO)2/PCy3 (Cy = cyclohexyl). The nature of the phosphane is decisive in these reactions : their basicity and cone angle must lie within a certain range. Initial products in the carbonylation are complexes 1 and 2." @default.
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- W2038063204 date "1989-10-01" @default.
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- W2038063204 title "Chlorocarbon Activation: Catalytic Carbonylation of Dichloromethane and Chlorobenzene" @default.
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- W2038063204 doi "https://doi.org/10.1002/anie.198913861" @default.
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