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- W2038091383 abstract "Abstract The strategies in the synthesis of metal carbide cluster are examined and the full synthesis procedures for a number of heteronuclear metal carbide clusters are presented. Specific classes of carbide clusters prepared are octahedral Fe 5 MC(CO) x y- and Fe 4 M 2 C(CO) x y- clusters and square pyramidal Fe 4 MC(CO) x y- clusters. One synthesis strategy was polyhedral expansion based on [Fe 4 C(CO) 12 2- ] or [Fe 5 C(CO) 14 2- ] reactions with coordinately unsaturated metal complexes or labile complexes that readily yield coordinately unsaturated complexes. Selected oxidative degradations of these octahedral carbide clusters provided a synthesis step comprising elision of an iron center to yield square pyramidal Fe 4 MC(CO) x y- clusters." @default.
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- W2038091383 date "1981-06-01" @default.
- W2038091383 modified "2023-10-09" @default.
- W2038091383 title "Metal carbide clusters synthesis systematics for heteronuclear species" @default.
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- W2038091383 doi "https://doi.org/10.1016/s0022-328x(00)93947-0" @default.
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