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• W2038158265 abstract "A series of crystalline aluminum hydroxy fluorides in cubic pyrochlore structure AlFx(OH)3−x·H2O with variable F-content x were investigated by solid-state NMR by applying different magnetic fields up to 21.1 T. Distinguishable octahedral species AlFx(OH)6−x (x = 1−6) were identified in the crystalline aluminum hydroxy fluorides. The subsequent analysis of the highfield 27Al MAS NMR data allows the derivation of the trend analysis graphs giving correlations between the 27Al chemical shifts and the quadrupolar frequencies and the F-content x in AlFx(OH)6−x. Clear trends were obtained for both, which are, along with the 19F MAS chemical-shift trend analysis presented earlier, valuable tools for the interpretation of MAS NMR spectra of amorphous AlFx(OX)3−x compounds (X = H, alkyl). Following the dehydration of the pyrochlores by solid-state NMR eventually reveals a remarkable influence of the incorporated solvent molecules (H2O) on the 19F chemical shift. On that basis, a new chemical-shift trend analysis for 19F chemical shifts in correlation with x in AlFx(OH)6−x units for proton-poor substances (in the Al, F, O, H system) was determined. By using this correlation, high-surface AlF3 has a mean bulk Al:F ratio similar to that found for ACF, namely, AlF2.8(O/OH)0.2." @default.
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• W2038158265 date "2008-09-13" @default.
• W2038158265 modified "2023-10-15" @default.
• W2038158265 title "Crystalline Aluminum Hydroxy Fluorides: Structural Insights Obtained by High Field Solid State NMR and Trend Analyses" @default.
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• W2038158265 doi "https://doi.org/10.1021/jp804662f" @default.
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