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- W2038180003 abstract "Mono- and 2,2′-disubstituted terminal alkenes can be isomerized into the more stable internal (Z)- and (E)-alkenes by treating them with catalytic amounts of [(allyl)PdCl]2 or [(allyl)NiBr]2, a triarylphosphine, and silver triflate at room temperature. The isomeric ratio (E:Z) depends on the alkenes, the E-isomer being the major one. The reaction is tolerant to a wide variety of functional groups including other reactive olefins. Unlike the more reactive Ir catalysts, monosubstituted alkenes give almost exclusively the 2-alkenes. Direct comparison to two of the best-known catalysts for this process {[Ir(PCy3)3]+[BPh4]− and Grubbs generation II metathesis catalyst} is also described." @default.
- W2038180003 created "2016-06-24" @default.
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- W2038180003 date "2009-05-14" @default.
- W2038180003 modified "2023-09-27" @default.
- W2038180003 title "Facile Pd(II)- and Ni(II)-Catalyzed Isomerization of Terminal Alkenes into 2-Alkenes" @default.
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- W2038180003 doi "https://doi.org/10.1021/jo900180p" @default.
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