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- W2038184003 abstract "Abstract The b-type Q-branch transitions of chloroiodomethane were remeasured and the quadrupole hyperfine structures were reinvestigated by a new method to improve the discrepancies in the hyperfine spectra observed and calculated in a previous work. The χ values of the off-diagonal element of 35Cl and 37Cl were determined. The nuclear quadrupole coupling constants were revised to be χaa = −1421.9 ± 1.9, χbb = 392.6 ± 1.0, χcc = 1029.3 ± 2.1, and {χab} = 1174.9 ± 1.7 MHz of iodine; χaa = −31.1 ± 1.1, χbb = −9.0 ± 0.6, χcc = 40.1 ± 1.2, and {χab} = 53.6 ± 4.2 MHz of 35Cl for 35Cl species; χaa = −1418.4 ± 2.5, χbb = 386.5 ± 2.7, χcc = 1031.9 ± 3.6, and {χab} = 1181.8 ± 1.7 MHz of iodine; and χaa = −21.1 ± 1.7, χbb = −8.5 ± 0.9, χcc = 29.6 ± 1.9, and {χab} = 34.6 ± 1.4 MHz of 37Cl for 37Cl species, respectively." @default.
- W2038184003 created "2016-06-24" @default.
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- W2038184003 date "1987-12-01" @default.
- W2038184003 modified "2023-10-14" @default.
- W2038184003 title "Reinvestigation of the quadrupole hyperfine structure in rotational spectra of chloroiodomethane" @default.
- W2038184003 doi "https://doi.org/10.1016/0022-2852(87)90237-2" @default.
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