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- W2038184477 abstract "Torsional structure in the supersonic jet spectra of 3-aminobenzotrifluoride has been interpreted. The CF3 torsional potentials are surprisingly similar to the CH3 potentials in 4-toluidine: there is a low barrier with a minimum near φ = 25° in S0, and a higher barrier with an eclipsed conformation in S1. However, because of the greater mass of the CF3 group, the spectra are quite different. Potential constants, in cm−1, are: V″3 = 9 ± 5, V″6 = −1 10 ± 2, V′3 = 155 ± 5, and V′6 = −40 ± 2, for F″ = F′ = 0.29 ± 0.01 cm−1." @default.
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- W2038184477 date "1991-09-01" @default.
- W2038184477 modified "2023-09-25" @default.
- W2038184477 title "CF3 torsional potentials in the S0 and S1 electronic states of 3-aminobenzotrifluoride" @default.
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- W2038184477 doi "https://doi.org/10.1016/0009-2614(91)90397-r" @default.
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