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• W2038185935 abstract "The tetrahedral heterobimetallic cluster (C5H5)NiRu3H3(CO)9, 1, when decomposed on KOH-modified γ-alumina, produces an effective heterogeneous catalyst for ammonia synthesis. Bimetallic particles have been evidenced on the support surface by analytical electron microscopy; their main size is 4.0 nm and their Ni/Ru atomic ratio is practically the same as that of the starting cluster. The treatment of unsupported 1 with alcoholic KOH gives a black, conductive, amorphous alloy powder. In this case, the ultrafine and bimetallic nature of the individual particles was also revealed by analytical TEM investigations." @default.
• W2038185935 created "2016-06-24" @default.
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• W2038185935 date "1991-09-01" @default.
• W2038185935 modified "2023-09-23" @default.
• W2038185935 title "Production of Ni-Ru bimetallic catalysts and materials by thermal and chemical decomposition of a tetranuclear bimetallic carbonyl cluster" @default.
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• W2038185935 doi "https://doi.org/10.1016/0254-0584(91)90021-l" @default.
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