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- W2038200066 abstract "Reaction of VCl3(THF)3 with one equivalent of R2NLi [R=i-Pr, Cy] formed the tetravalent (R2N)2VCl2 [R=i-Pr (1a), Cy (1b)] which was isolated in crystalline form. The formation of these species is likely to be ascribed to a disproportionation reaction since a divalent vanadium complex, VCl2(TMEDA)2 complex was isolated upon treatment of the reaction mixtures with TMEDA. Complexes 1 can be alkylated with RLi to yield the corresponding (R2N)2VR2 (2) derivatives in good yield. Preliminary data on ethylene–propylene (EP) co-polymerization obtained with compounds 1 in conjunction with various aluminum alkyl compounds are described." @default.
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- W2038200066 date "1998-07-01" @default.
- W2038200066 modified "2023-10-08" @default.
- W2038200066 title "Preparation and characterization of (R2N)2VCl2 [R=Cy, i-Pr] and its activity as olefin polymerization catalyst" @default.
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- W2038200066 doi "https://doi.org/10.1016/s0022-328x(98)00366-0" @default.
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