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- W2038236211 abstract "The unimolecular decompositions upon electron impact of the bifunctional compounds ØCH2-NH(CH2)n-OCH2Ø(n=2 to 7)have been studied by deuterium labelling. The molecular ions lose a benzyl radical and/or a benzaldehyde molecule, depending on the length of the aliphatic chain. Both reactions appear to be the result of the transfer of a hydrogen atom to the charge localized amino function in a cyclic transition state. The ring size of this transition state turns out to play a far more important role than the difference in reactivity of the migrating hydrogen atoms." @default.
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- W2038236211 date "1976-03-01" @default.
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- W2038236211 title "Chain length effects in the competition between intramolecular hydrogen migrations in the molecular ions of hydrogen migration in the molecular ions of α-benzylamino-ω-benzyloxyalkanes as studied by deuterium labelling" @default.
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- W2038236211 doi "https://doi.org/10.1002/oms.1210110307" @default.
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