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- W2038247342 abstract "The pentacyclic unsaturated ketone 3 is obtained as the sole product by the reaction of pinocarvone (1) with cycloocta-triene in the presence of catalytic amounts of dicarbonyl-bis(η4-pinocarvone)molybdenum (2). Compound 3 formally resulting from a [4 + 2] cycloaddition reaction of bicy-clo[4.2.0]octa-2,4-diene with the alkene fragment of pinocarvone was characterised by means of spectroscopy (1H, 13CNMR, IR, MS) as well as by X-ray crystal structure analysis. A mechanism is proposed involving rigid molybdenum complexes as intermediates in order to explain the stereospecificity of the reaction." @default.
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- W2038247342 date "1995-09-01" @default.
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- W2038247342 title "A Molybdenum‐Catalysed Electrocyclisation‐Cycloaddition Sequence: Synthesis and Structure of a Pentacyclic Unsaturated Ketone" @default.
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- W2038247342 doi "https://doi.org/10.1002/cber.19951280917" @default.
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