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- W2038291266 abstract "This paper describes the transient properties of the second-order nonlinear optical processes of a diazo-dye-substituted poled polymer. The temperature dependences of bulk susceptibilities and Pockels coefficients are measured below the glass transition temperature to estimate relaxation times. The activation energy of 43 kcal/mol determined from the Arrhenius plots of the relaxation times is assigned to that of the α relaxation of the diazo-dye-substituted polymer. The relaxation of the induced alignment of diazo-dye side groups is restricted because of both the large dye molecular volume of greater than 500 Å3 and the very small cumulative distribution of local free volumes which are greater than the dye molecular volume in the polymer." @default.
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- W2038291266 date "1996-04-15" @default.
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- W2038291266 title "Relaxation process for second-order nonlinear optical properties of poled diazo-dye-substituted polymers" @default.
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- W2038291266 doi "https://doi.org/10.1063/1.361745" @default.
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