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- W2038292287 abstract "Electrical conductivity and thermoelectric power measurements have been made on nonstoichiometric UO2 at temperatures of 500–1150°C. The conductivity data in the single phase UO2+x region can be represented by the equation σ(ohm cm)−1=(3.8×106)/T(2x)(1−2x) exp[(−0.30±0.03 ev)/kT].An approximate equation for the thermoelectric power Q, is Q=(k/e) ln(1−2x/2x). The electrical measurements confirm the ionic theory of nonstoichiometry in UO2, postulated on the basis of thermodynamic evidence. Nonstoichiometric UO2 is a relatively simple ionic solid in which activated electronic hole transfer occurs between U5+ and U4+ ions in the lattice." @default.
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- W2038292287 date "1961-10-01" @default.
- W2038292287 modified "2023-10-10" @default.
- W2038292287 title "Electrical Properties of Nonstoichiometric Uranium Dioxide" @default.
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- W2038292287 doi "https://doi.org/10.1063/1.1732057" @default.
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