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- W2038296188 abstract "Rheological properties of chitosan acetate solutions containing chitin nanofibrils (n-chitin) and biocompatible plasticizers intended for preparation of biodegradable films are reported in the steady, oscillatory and transient shear flow. The experiments were performed on slurries with an optimum proportion of 65/35 wt.% between chitosan and n-chitin in the films which was determined from our results of mechanical properties and absorption of water vapor. The time-dependent dynamic experiments revealed the chitin nanofibrils as an effective gelling agent of chitosan phase. The phenomenon is explained by a chitosan-like surface of n-chitin and by the interactions inducing orientational cooperativity of chitosan molecules dissolved in close neighborhood of the anisotropic chitin nanofibrils. Additions of glycerol or poly(ethylene glycol), improving mechanical properties of the films, delay significantly the onset of gelation of chitosan/n-chitin slurries. The effect is induced by an increase in viscosity of the slurries and by their enhanced chaotropic character." @default.
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- W2038296188 date "2014-11-01" @default.
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- W2038296188 title "Rheological study of chitosan acetate solutions containing chitin nanofibrils" @default.
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- W2038296188 doi "https://doi.org/10.1016/j.carbpol.2014.06.043" @default.
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