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- W2038297681 abstract "The synthesis of three new silver(I) complexes with corannulene is reported. In the crystal these complexes form extended networks of Ag(+) ions, corannulene nuclei, and counterions, similar to the networks reported for Ag(+) with other polynuclear aromatic hydrocarbons (PAHs). The preferred Ag(+)-arene interaction is compared with the model developed by Kochi. The crystal motifs can be described by a classification scheme analogous to that developed by Etter for hydrogen-bonded networks in solids. The effect of counterion variation (ClO(4)(-), O(3)SCF(3)(-), BF(4)(-)) is noted to be substantial. Thus, although one can categorize the various networks, it is hard to predict an expected packing pattern on the basis of preferred binding in the metal/organic complex alone." @default.
- W2038297681 created "2016-06-24" @default.
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- W2038297681 date "2005-01-01" @default.
- W2038297681 modified "2023-10-16" @default.
- W2038297681 title "Anion mediated structural motifs in silver(<scp>i</scp>) complexes with corannulene" @default.
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- W2038297681 doi "https://doi.org/10.1039/b411987h" @default.
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