FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2038303118> ?p ?o ?g. }

• W2038303118 endingPage "2084" @default.
• W2038303118 startingPage "2080" @default.
• W2038303118 abstract "The asymmetric hydrolysis of dimethyl 3-phenylglutarate 1 catalyzed by different immobilized preparations of Rhizopus oryzae lipase (ROL) has been studied. The Lewatit CNP 105 commercial support was activated to aldehyde groups (Lewatit-aldehyde) and used as a support for the immobilization of ROL using different strategies. Thus, the lipase immobilized in the presence of dithiothreitol at pH 7 (ROL-Lew-pH 7) was the most enantioselective catalyst for the hydrolysis of 1 at pH 7 and 25 °C producing the (R)-monoester with an E value of 4.2 (ee = 62%) whereas ROL immobilized at pH 10 gave only an E value of 1.1 (ee = 4%). The medium engineering was also an interesting tool for improving the lipase selectivity. The addition of a solvent, combined with decreasing temperature improved the E value for the reaction from 4.2 to 24 (ee = 62 to ee = 92%). Finally, the application of the ROL-Lew-pH 7 preparation in the presence of 20% dioxane and 5 °C allowed us to obtain the (R)-isomer of the monoester with an E value of 24 (ee = 92%) in a 97% yield (of monoesters)." @default.
• W2038303118 created "2016-06-24" @default.
• W2038303118 creator A5003289620 @default.
• W2038303118 creator A5028391028 @default.
• W2038303118 date "2011-12-01" @default.
• W2038303118 modified "2023-10-14" @default.
• W2038303118 title "Enantioselective desymmetrization of prochiral diesters catalyzed by immobilized Rhizopus oryzae lipase" @default.
• W2038303118 cites W1549240509 @default.
• W2038303118 cites W1559643969 @default.
• W2038303118 cites W1967863865 @default.
• W2038303118 cites W1972981514 @default.
• W2038303118 cites W1996644470 @default.
• W2038303118 cites W1998065030 @default.
• W2038303118 cites W2003972102 @default.
• W2038303118 cites W2014128067 @default.
• W2038303118 cites W2025877107 @default.
• W2038303118 cites W2033822967 @default.
• W2038303118 cites W2042840613 @default.
• W2038303118 cites W2043451183 @default.
• W2038303118 cites W2046820889 @default.
• W2038303118 cites W2050826925 @default.
• W2038303118 cites W2055018594 @default.
• W2038303118 cites W2063597962 @default.
• W2038303118 cites W2065106071 @default.
• W2038303118 cites W2068447470 @default.
• W2038303118 cites W2069180449 @default.
• W2038303118 cites W2070690945 @default.
• W2038303118 cites W2071951841 @default.
• W2038303118 cites W2081186248 @default.
• W2038303118 cites W2081815886 @default.
• W2038303118 cites W2087641698 @default.
• W2038303118 cites W2094505809 @default.
• W2038303118 cites W2110558005 @default.
• W2038303118 cites W2135497760 @default.
• W2038303118 cites W2149724710 @default.
• W2038303118 cites W2316038605 @default.
• W2038303118 cites W2953364345 @default.
• W2038303118 doi "https://doi.org/10.1016/j.tetasy.2011.11.012" @default.
• W2038303118 hasPublicationYear "2011" @default.
• W2038303118 type Work @default.
• W2038303118 sameAs 2038303118 @default.
• W2038303118 citedByCount "22" @default.
• W2038303118 countsByYear W20383031182012 @default.
• W2038303118 countsByYear W20383031182013 @default.
• W2038303118 countsByYear W20383031182014 @default.
• W2038303118 countsByYear W20383031182015 @default.
• W2038303118 countsByYear W20383031182016 @default.
• W2038303118 countsByYear W20383031182017 @default.
• W2038303118 countsByYear W20383031182018 @default.
• W2038303118 countsByYear W20383031182019 @default.
• W2038303118 countsByYear W20383031182020 @default.
• W2038303118 countsByYear W20383031182022 @default.
• W2038303118 crossrefType "journal-article" @default.
• W2038303118 hasAuthorship W2038303118A5003289620 @default.
• W2038303118 hasAuthorship W2038303118A5028391028 @default.
• W2038303118 hasConcept C100544194 @default.
• W2038303118 hasConcept C146686406 @default.
• W2038303118 hasConcept C161790260 @default.
• W2038303118 hasConcept C178790620 @default.
• W2038303118 hasConcept C181199279 @default.
• W2038303118 hasConcept C185592680 @default.
• W2038303118 hasConcept C2777190055 @default.
• W2038303118 hasConcept C2778541762 @default.
• W2038303118 hasConcept C2779697368 @default.
• W2038303118 hasConcept C2779825165 @default.
• W2038303118 hasConcept C2780471494 @default.
• W2038303118 hasConcept C2991821551 @default.
• W2038303118 hasConcept C94412978 @default.
• W2038303118 hasConceptScore W2038303118C100544194 @default.
• W2038303118 hasConceptScore W2038303118C146686406 @default.
• W2038303118 hasConceptScore W2038303118C161790260 @default.
• W2038303118 hasConceptScore W2038303118C178790620 @default.
• W2038303118 hasConceptScore W2038303118C181199279 @default.
• W2038303118 hasConceptScore W2038303118C185592680 @default.
• W2038303118 hasConceptScore W2038303118C2777190055 @default.
• W2038303118 hasConceptScore W2038303118C2778541762 @default.
• W2038303118 hasConceptScore W2038303118C2779697368 @default.
• W2038303118 hasConceptScore W2038303118C2779825165 @default.
• W2038303118 hasConceptScore W2038303118C2780471494 @default.
• W2038303118 hasConceptScore W2038303118C2991821551 @default.
• W2038303118 hasConceptScore W2038303118C94412978 @default.
• W2038303118 hasIssue "24" @default.
• W2038303118 hasLocation W20383031181 @default.
• W2038303118 hasOpenAccess W2038303118 @default.
• W2038303118 hasPrimaryLocation W20383031181 @default.
• W2038303118 hasRelatedWork W1571841850 @default.
• W2038303118 hasRelatedWork W177888362 @default.
• W2038303118 hasRelatedWork W1977510854 @default.
• W2038303118 hasRelatedWork W1988337357 @default.
• W2038303118 hasRelatedWork W1999044781 @default.
• W2038303118 hasRelatedWork W2056125069 @default.
• W2038303118 hasRelatedWork W2089545573 @default.
• W2038303118 hasRelatedWork W2375305915 @default.
• W2038303118 hasRelatedWork W2932435379 @default.
• W2038303118 hasRelatedWork W803856426 @default.
• W2038303118 hasVolume "22" @default.
• W2038303118 isParatext "false" @default.
• W2038303118 isRetracted "false" @default.

• next