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- W2038426847 abstract "The previously unknown compound Ba5IrIn2Al2O13Cl was prepared as single crystals and investigated by means of X-rays (space group D6h4-P63/mmc; a=5.860 Å; c=25.101 Å; Z=2). In the giant molecule, face-sharing triple octahedra, arranged around Ir5+ and In3+, are connected at the corners to Al2O7 double tetrahedra. There are three different barium positions which are coordinated in a characteristic way to O2− and Cl−. The relationship of this to other structures containing face-sharing octahedra is discussed. Die bislang unbekannte Verbindung Ba5IrIn2Al2O13Cl wurde einkristallin dargestellt und röntgenographisch untersucht (Raumgruppe D6h4-P63/mmc; a=5,860 Å; c=25,101 Å; Z=2). Flächenverknüpfte, geordnet mit Ir5+ und In3+ besetzte Oktaedertripel sind im Kristallverband mit Al2O7-Tetraederdoppeln über Ecken verknüpft. Es treten drei verschiedene Bariumlagen auf, die durch O2− und Cl− in charakteristischer Weise koordiniert sind. Der Zusammenhang mit anderen Strukturen, die flächenverknüpfte Oktaeder aufweisen, wird diskturiert." @default.
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- W2038426847 date "1992-05-01" @default.
- W2038426847 modified "2023-09-24" @default.
- W2038426847 title "Ein neues Erdalkalimetall-Chlorooxometallat mit Ir5+: Ba5IrIn2Al2O13Cl" @default.
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- W2038426847 doi "https://doi.org/10.1016/0925-8388(92)90726-p" @default.
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