FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2038434514> ?p ?o ?g. }

• W2038434514 endingPage "1160" @default.
• W2038434514 startingPage "1152" @default.
• W2038434514 abstract "Abstract The electronic properties of four divinylanthracene‐bridged diruthenium carbonyl complexes [{RuCl(CO)(PMe 3 ) 3 } 2 (μCHCHArCHCH)] (Ar=9,10‐anthracene ( 1 ), 1,5‐anthracene ( 2 ), 2,6‐anthracene ( 3 ), 1,8‐anthracene ( 4 )) obtained by molecular spectroscopic methods (IR, UV/Vis/near‐IR, and EPR spectroscopy) and DFT calculations are reported. IR spectroelectrochemical studies have revealed that these complexes are first oxidized at the noninnocent bridging ligand, which is in line with the very small ν (CO) wavenumber shift that accompanies this process and also supported by DFT calculations. Because of poor conjugation in complex 1 , except oxidized 1 + , the electronic absorption spectra of complexes 2 + , 3 + , and 4 + all display the characteristic near‐IR band envelopes that have been deconvoluted into three Gaussian sub‐bands. Two of the sub‐bands belong mainly to metal‐to‐ligand charge‐transfer (MLCT) transitions according to results from time‐dependent DFT calculations. EPR spectroscopy of chemically generated 1 + – 4 + proves largely ligand‐centered spin density, again in accordance with IR spectra and DFT calculations results." @default.
• W2038434514 created "2016-06-24" @default.
• W2038434514 creator A5000251455 @default.
• W2038434514 creator A5015395467 @default.
• W2038434514 creator A5019091031 @default.
• W2038434514 creator A5061813492 @default.
• W2038434514 creator A5065419027 @default.
• W2038434514 creator A5087751395 @default.
• W2038434514 creator A5090046474 @default.
• W2038434514 creator A5090618642 @default.
• W2038434514 date "2014-01-21" @default.
• W2038434514 modified "2023-10-18" @default.
• W2038434514 title "Bridge-Localized HOMO-Binding Character of Divinylanthracene-Bridged Dinuclear Ruthenium Carbonyl Complexes: Spectroscopic, Spectroelectrochemical, and Computational Studies" @default.
• W2038434514 cites W1855537652 @default.
• W2038434514 cites W1967169607 @default.
• W2038434514 cites W1968238359 @default.
• W2038434514 cites W1971848159 @default.
• W2038434514 cites W1978328601 @default.
• W2038434514 cites W1979568951 @default.
• W2038434514 cites W1982353235 @default.
• W2038434514 cites W1983444156 @default.
• W2038434514 cites W1989340313 @default.
• W2038434514 cites W1994628146 @default.
• W2038434514 cites W1999728492 @default.
• W2038434514 cites W2001675098 @default.
• W2038434514 cites W2002045032 @default.
• W2038434514 cites W2002266779 @default.
• W2038434514 cites W2002453481 @default.
• W2038434514 cites W2005354604 @default.
• W2038434514 cites W2006383203 @default.
• W2038434514 cites W2011227483 @default.
• W2038434514 cites W2016547684 @default.
• W2038434514 cites W2018815967 @default.
• W2038434514 cites W2021919636 @default.
• W2038434514 cites W2023971512 @default.
• W2038434514 cites W2030472778 @default.
• W2038434514 cites W2032498497 @default.
• W2038434514 cites W2043725874 @default.
• W2038434514 cites W2046781685 @default.
• W2038434514 cites W2048158093 @default.
• W2038434514 cites W2052752040 @default.
• W2038434514 cites W2055550841 @default.
• W2038434514 cites W2062866104 @default.
• W2038434514 cites W2063074480 @default.
• W2038434514 cites W2063151161 @default.
• W2038434514 cites W2065085089 @default.
• W2038434514 cites W2071012189 @default.
• W2038434514 cites W2072301098 @default.
• W2038434514 cites W2073643119 @default.
• W2038434514 cites W2076118813 @default.
• W2038434514 cites W2076339719 @default.
• W2038434514 cites W2078451807 @default.
• W2038434514 cites W2079774127 @default.
• W2038434514 cites W2088481620 @default.
• W2038434514 cites W2088791877 @default.
• W2038434514 cites W2099454651 @default.
• W2038434514 cites W2100032486 @default.
• W2038434514 cites W2134300039 @default.
• W2038434514 cites W213791877 @default.
• W2038434514 cites W2143473913 @default.
• W2038434514 cites W2148469323 @default.
• W2038434514 cites W2161253705 @default.
• W2038434514 cites W2166734608 @default.
• W2038434514 cites W2169474890 @default.
• W2038434514 cites W2273025874 @default.
• W2038434514 cites W2315376204 @default.
• W2038434514 cites W2316343512 @default.
• W2038434514 cites W2319983723 @default.
• W2038434514 cites W2327380216 @default.
• W2038434514 cites W2328919357 @default.
• W2038434514 cites W2333982190 @default.
• W2038434514 cites W2334281912 @default.
• W2038434514 cites W2334707776 @default.
• W2038434514 cites W2335100551 @default.
• W2038434514 cites W4238005405 @default.
• W2038434514 doi "https://doi.org/10.1002/asia.201301544" @default.
• W2038434514 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24449396" @default.
• W2038434514 hasPublicationYear "2014" @default.
• W2038434514 type Work @default.
• W2038434514 sameAs 2038434514 @default.
• W2038434514 citedByCount "28" @default.
• W2038434514 countsByYear W20384345142014 @default.
• W2038434514 countsByYear W20384345142015 @default.
• W2038434514 countsByYear W20384345142016 @default.
• W2038434514 countsByYear W20384345142017 @default.
• W2038434514 countsByYear W20384345142019 @default.
• W2038434514 countsByYear W20384345142020 @default.
• W2038434514 countsByYear W20384345142023 @default.
• W2038434514 crossrefType "journal-article" @default.
• W2038434514 hasAuthorship W2038434514A5000251455 @default.
• W2038434514 hasAuthorship W2038434514A5015395467 @default.
• W2038434514 hasAuthorship W2038434514A5019091031 @default.
• W2038434514 hasAuthorship W2038434514A5061813492 @default.
• W2038434514 hasAuthorship W2038434514A5065419027 @default.
• W2038434514 hasAuthorship W2038434514A5087751395 @default.
• W2038434514 hasAuthorship W2038434514A5090046474 @default.
• W2038434514 hasAuthorship W2038434514A5090618642 @default.
• W2038434514 hasConcept C116569031 @default.

• next