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- W2038451368 abstract "The reactions under anhydrous conditions of methyl α-d-glucoside, methyl α-d-mannoside, sucrose, cellobiose, O-methylcellulose, and purified cotton cellulose with such boron alkoxides as boron ethoxide, boron propoxide, and boron isopropoxide were investigated. The neat boron alkoxide, or a solution of the alkoxide in the parent alcohol, benzene, pyridine, ethylenediamine, or pyridineethylenediamine was used as the solvent in different experiments. With increase in molecular weight, reaction of the carbohydrate with boron alkoxides (neat, in benzene, or in the parent alcohol) either did not occur or was decreased, its extent being very low for higher members. In pyridine or ethylenediamine, the reactivity of carbohydrates toward boron alkoxides was increased. Cellulose did not react with the neat alkoxides, and, in pyridine, reacted with them to only a small extent, but in ethylenediamine, cellulose (both ground and in fiber form) reacted with the alkoxides." @default.
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- W2038451368 date "1971-10-01" @default.
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- W2038451368 title "Reactions of carbohydrates, including cellulose, with boron alkoxides under anhydrous conditions" @default.
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- W2038451368 doi "https://doi.org/10.1016/s0008-6215(00)86166-2" @default.
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