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• W2038452317 endingPage "814" @default.
• W2038452317 startingPage "811" @default.
• W2038452317 abstract "The geometry and electronic properties of methylene, methylcarbene, carboxycarbene, phenylcarbene, trimethylsilylcarbene, silylcarbene, carboxysilylcarbene, and phenylsilylcarbene have been determined by MINDO/3 calculation. Introduction of a silyl group results in considerable decrease in ionization potential of carbenes. The electron affinity is increased to some extent by such substitution. The computation suggests a bent geometry for optimized triplet trimethylsilylcarbene structure, in conflict with a recent postulate that the ground-state molecule has an essentially linear structure." @default.
• W2038452317 created "2016-06-24" @default.
• W2038452317 creator A5004784825 @default.
• W2038452317 creator A5054350731 @default.
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• W2038452317 date "1978-03-01" @default.
• W2038452317 modified "2023-10-12" @default.
• W2038452317 title "A Molecular Orbital Study of Silylated Carbenes" @default.
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• W2038452317 doi "https://doi.org/10.1246/bcsj.51.811" @default.
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