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- W2038474004 abstract "Diversity-oriented organic synthesis (DOS) is a key concept for construction of skeletally diverse small molecule libraries to discover drug-like small molecules. Here, we describe a DOS class to transform a complex 7-oxanorbornene skeleton, which is readily accessible by a tandem Ugi/Diels–Alder reaction, into two heterotricycle skeletons selectively by using tandem ROM/CM/RCM reaction. In the present study, the mode of cyclization is pre-encoded by building blocks used in the complexity-generating tandem Ugi/Diels–Alder reaction. Since variable alkenes can be used in the CM reaction, our approach can be extended to construct both skeleton- and appendage-diverse small molecule libraries." @default.
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- W2038474004 date "2005-08-01" @default.
- W2038474004 modified "2023-10-09" @default.
- W2038474004 title "Simultaneous accumulation of both skeletal and appendage-based diversities on tandem Ugi/Diels–Alder products" @default.
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- W2038474004 doi "https://doi.org/10.1016/j.tetlet.2005.06.147" @default.
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