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• W2038492258 endingPage "874" @default.
• W2038492258 startingPage "863" @default.
• W2038492258 abstract "Metal-mediated coupling between one or two isonitrile ligands in cis-[MCl2(C≡NR)2] [M = Pd, Pt; R = 2,6-Me2C6H3 (Xyl), But, cyclohexyl (Cy)] and N-phenylbenzamidine, HN═C(Ph)NHPh, proceeds with different regioselectivity upon varying R group. When the aromatic isonitrile is used (R = Xyl), N-phenylbenzamidine is coordinated to a metal by the HN═C moiety, and the nucleophilic attack proceeds via the NHPh center of the benzamidine giving [MCl{C(N(Ph)C(Ph)═NH)═NXyl}(C≡NXyl)]. For R = But, HN═C(Ph)NHPh is coordinated to a metal by the NHPh center, and the addition occurs via the HN═C center of the nucleophile to afford [MCl{C(NC(Ph)═NPh)═NBut}(C≡NBut)]. With R = Cy, a mixture of two products that are derived from the addition of N-phenylbenzamidine by two nucleophilic centers was detected. The substituent R dependent reactivity was explored using theoretical (DFT) methods and interpreted as a result of the steric repulsions in one of the regioisomers of the addition products, when R = Cy and But. All prepared..." @default.
• W2038492258 created "2016-06-24" @default.
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• W2038492258 creator A5045499776 @default.
• W2038492258 creator A5050557480 @default.
• W2038492258 date "2011-01-28" @default.
• W2038492258 modified "2023-09-25" @default.
• W2038492258 title "Substituent R-Dependent Regioselectivity Switch in Nucleophilic Addition of <i>N</i>-Phenylbenzamidine to Pd^II- and Pt^II-Complexed Isonitrile RN≡C Giving Aminocarbene-Like Species" @default.
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• W2038492258 doi "https://doi.org/10.1021/om101041g" @default.
• W2038492258 hasPublicationYear "2011" @default.
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