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• W2038509084 abstract "The reorientation process of a molecular probe dissolved in the fragile glass former o-terphenyl is studied via electron spin-resonance spectroscopy. Owing to the good resolution of the ESR lineshape in the so-called slow-motion regime, we are able to discriminate between diffusive and jump rotations. In the region of the glass transition ( the results are at variance with the diffusion models and are fairly well reproduced by assuming that the probe jumps with steps . The temperature dependence of the correlation time is well described, in the temperature range investigated, by a double Arrhenius law broken at . The findings are compared with previous NMR, dielectric, fluorescence and molecular dynamics studies." @default.
• W2038509084 created "2016-06-24" @default.
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• W2038509084 date "1996-05-20" @default.
• W2038509084 modified "2023-10-03" @default.
• W2038509084 title "Jump reorientation of a molecular probe in the glass transition region of<i>o</i>-terphenyl" @default.
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• W2038509084 doi "https://doi.org/10.1088/0953-8984/8/21/007" @default.
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