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- W2038551212 endingPage "1008" @default.
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- W2038551212 abstract "Electromotive force measurements at 25 °C of the transference cells Ag|AgCl|MeCl (m2)|MeCl (m1)|AgCl|Ag and MexHg1-x|MeCl (m1)|MeCl (m2)|MexHg1-x (where Me = Li, Na, K, and Rb and MexHg1-x denotes a flowing Me-amalgam electrode at Me mole fraction x) have been made at various molalities m2 > m1 (with m1 fixed and m2 varied) in methanol + water solvent mixtures with methanol mass fractions wM up to 0.8. Supplementary emf measurements have been made of the cell Pt|LixHg1-x|LiCl (m1)|AgCl|Ag|Pt to obtain the required activity coefficients for LiCl at methanol mass fractions wM = 0.2. The general trend of the ionic transference numbers of each MeCl is a t°Me+ increase with wM, which is much more pronounced for those Me+'s whose primary hydration sheaths are bigger (namely, Li+ and Na+). In particular, KCl becomes exactly equitransferent (t°K+ = t°Cl− = 0.5, i.e. an ideal salt bridge) at wM ≈ 0.1, but at wM > 0.6 the KCl solubility becomes insufficient for a salt bridge function. The same drawback occurs also for RbCl, which is known to be the most closely equitransferent salt in water (t°Rb+ = 0.5007). NaCl, which is quite unproposable as a salt bridge in water, may be useful at high methanol concentrations, as its ionic transference numbers would approach 0.5 at wM ≥ 0.8." @default.
- W2038551212 created "2016-06-24" @default.
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- W2038551212 date "1999-07-30" @default.
- W2038551212 modified "2023-09-27" @default.
- W2038551212 title "Transference Numbers of Alkali Chlorides and Characterization of Salt Bridges for Use in Methanol + Water Mixed Solvents" @default.
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- W2038551212 doi "https://doi.org/10.1021/je9900979" @default.
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