Matches in SemOpenAlex for { <https://semopenalex.org/work/W2038601265> ?p ?o ?g. }
Showing items 1 to 89 of
89
with 100 items per page.
- W2038601265 endingPage "458" @default.
- W2038601265 startingPage "435" @default.
- W2038601265 abstract "The J = 3 ← 2 transitions of CF3H and CF3D in the v6 = 1 state have been observed and analyzed. Direct l-type resonance transitions have also been observed for the v6 = 1 state of CF3H from J = 19 through J = 32 and from J = 29 through J = 35 for CF3D. In addition, splittings of the K = 3 transitions were observed which have been accounted for by including the l-type interaction, Δl = 2, ΔK = −4, between the l = −1, K = 2 and l = 1, K = −2 levels. Their frequencies were analyzed by taking into account the (2,2), (2, −1), and (2, −4) interactions and some third-order terms. From the analysis the product q6l6 was determined to be negative. Furthermore, two transitions of CF3D, J = 34, K = 0 and 3, were found shifted by accidental degeneracy through an r-type interaction, and the analysis gave C6 = 5662.0 ± 0.9 MHz, and the Coriolis coupling constant ζ6 = −0.7524 ± 0.0003 for CF3D and an improved value of ζ6 = −0.8053 ± 0.0004 for CF3H. The values of |q6| and |r6| were found to be 36.27917 ± 0.00013 and 0.97 ± 0.02 MHz for CF3H, and 31.8465 ± 0.0003 and 1.297 ± 0.002 MHz for CF3D. The three cubic constants k666, k466, and k566 have been evaluated using the q6 and r6 values obtained for both molecules. Finally, certain unusual features of the Stark effect have been investigated; the unusually slow Stark effect observed for the ΔJ = 0, K ≠ 3 transitions of CF3D and “forbidden” Stark transitions which appear for quickly modulated lines in both CF3D and CF3H. Frequencies of the “forbidden” lines have been accounted for by introducing the ω-type interaction, Δl = 0, ΔK = 6 between l = ±1, K = ⊣2 and l = ±1, K =±4 states, with differences in the upper and lower doublet splittings substantiated by rf/mw double resonance." @default.
- W2038601265 created "2016-06-24" @default.
- W2038601265 creator A5042922036 @default.
- W2038601265 creator A5061634903 @default.
- W2038601265 date "1976-06-01" @default.
- W2038601265 modified "2023-09-25" @default.
- W2038601265 title "Microwave spectra of CF3H and CF3D in the v6 = 1 state: Direct l-type resonance transitions and J = 3 ← 2 transition" @default.
- W2038601265 cites W1495992936 @default.
- W2038601265 cites W1516384680 @default.
- W2038601265 cites W1560012533 @default.
- W2038601265 cites W1971962558 @default.
- W2038601265 cites W1980119694 @default.
- W2038601265 cites W1982969242 @default.
- W2038601265 cites W1985642968 @default.
- W2038601265 cites W1988828760 @default.
- W2038601265 cites W1995418228 @default.
- W2038601265 cites W1999653286 @default.
- W2038601265 cites W2011925781 @default.
- W2038601265 cites W201385752 @default.
- W2038601265 cites W2014258604 @default.
- W2038601265 cites W2024645708 @default.
- W2038601265 cites W2068189957 @default.
- W2038601265 cites W2068328948 @default.
- W2038601265 cites W2073990172 @default.
- W2038601265 cites W2086321433 @default.
- W2038601265 cites W2086869078 @default.
- W2038601265 cites W2580901971 @default.
- W2038601265 doi "https://doi.org/10.1016/0022-2852(76)90334-9" @default.
- W2038601265 hasPublicationYear "1976" @default.
- W2038601265 type Work @default.
- W2038601265 sameAs 2038601265 @default.
- W2038601265 citedByCount "18" @default.
- W2038601265 countsByYear W20386012652014 @default.
- W2038601265 crossrefType "journal-article" @default.
- W2038601265 hasAuthorship W2038601265A5042922036 @default.
- W2038601265 hasAuthorship W2038601265A5061634903 @default.
- W2038601265 hasConcept C10138342 @default.
- W2038601265 hasConcept C11413529 @default.
- W2038601265 hasConcept C121332964 @default.
- W2038601265 hasConcept C139210041 @default.
- W2038601265 hasConcept C162324750 @default.
- W2038601265 hasConcept C182306322 @default.
- W2038601265 hasConcept C183276030 @default.
- W2038601265 hasConcept C184779094 @default.
- W2038601265 hasConcept C18903297 @default.
- W2038601265 hasConcept C2777299769 @default.
- W2038601265 hasConcept C41008148 @default.
- W2038601265 hasConcept C44838205 @default.
- W2038601265 hasConcept C48103436 @default.
- W2038601265 hasConcept C4839761 @default.
- W2038601265 hasConcept C62520636 @default.
- W2038601265 hasConcept C86803240 @default.
- W2038601265 hasConceptScore W2038601265C10138342 @default.
- W2038601265 hasConceptScore W2038601265C11413529 @default.
- W2038601265 hasConceptScore W2038601265C121332964 @default.
- W2038601265 hasConceptScore W2038601265C139210041 @default.
- W2038601265 hasConceptScore W2038601265C162324750 @default.
- W2038601265 hasConceptScore W2038601265C182306322 @default.
- W2038601265 hasConceptScore W2038601265C183276030 @default.
- W2038601265 hasConceptScore W2038601265C184779094 @default.
- W2038601265 hasConceptScore W2038601265C18903297 @default.
- W2038601265 hasConceptScore W2038601265C2777299769 @default.
- W2038601265 hasConceptScore W2038601265C41008148 @default.
- W2038601265 hasConceptScore W2038601265C44838205 @default.
- W2038601265 hasConceptScore W2038601265C48103436 @default.
- W2038601265 hasConceptScore W2038601265C4839761 @default.
- W2038601265 hasConceptScore W2038601265C62520636 @default.
- W2038601265 hasConceptScore W2038601265C86803240 @default.
- W2038601265 hasIssue "3" @default.
- W2038601265 hasLocation W20386012651 @default.
- W2038601265 hasOpenAccess W2038601265 @default.
- W2038601265 hasPrimaryLocation W20386012651 @default.
- W2038601265 hasRelatedWork W1979854777 @default.
- W2038601265 hasRelatedWork W1979919710 @default.
- W2038601265 hasRelatedWork W1997086491 @default.
- W2038601265 hasRelatedWork W2050648543 @default.
- W2038601265 hasRelatedWork W2057959975 @default.
- W2038601265 hasRelatedWork W2064702971 @default.
- W2038601265 hasRelatedWork W2088363837 @default.
- W2038601265 hasRelatedWork W2093181719 @default.
- W2038601265 hasRelatedWork W2316676232 @default.
- W2038601265 hasRelatedWork W2359055758 @default.
- W2038601265 hasVolume "61" @default.
- W2038601265 isParatext "false" @default.
- W2038601265 isRetracted "false" @default.
- W2038601265 magId "2038601265" @default.
- W2038601265 workType "article" @default.