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- W2038607384 abstract "Novel ferrocene modified P,N-ligands (R,R,Sp)-8 and (S,S,Sp)-9 were synthesized conveniently from enantiopure cyclohexanediamine and (Sp)-2-phosphinoferrocenyl carboxylic acid. They were used as chiral ligands for palladium-catalyzed allylic substitutions of rac-1, 3-diphenylprop-2-enyl acetate with dimethylmalonate and benzylamine. (R,R,Sp)-8 was found to be a better ligand containing matched chiralities (central chirality and planar chirality) and showed a higher enantioselectivity." @default.
- W2038607384 created "2016-06-24" @default.
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- W2038607384 date "2001-12-01" @default.
- W2038607384 modified "2023-10-18" @default.
- W2038607384 title "Novel ferrocene modified P,N-ligands for enantioselective palladium-catalyzed allylic substitution reactions" @default.
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- W2038607384 doi "https://doi.org/10.1016/s0022-328x(01)00911-1" @default.
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