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- W2038638071 abstract "Nanostructured hybrid organic–inorganic solids are a class of materials of growing interest because of their great potential in synthesis and applications. All the molecular organic precursors containing at least two Si(OR)3 groups can be transformed into silica-based hybrid materials by hydrolytic sol–gel polycondensation. These materials exhibit the chemical and physical properties of the organic units included in the silica matrix. They present both nanometric and micrometric scale organization in the solid state, whatever the nature and the geometry of the organic units (linear, twisted, planar and even tetrahedral). These materials are prepared under kinetic control with a corresponding organization that is completely different to crystalline order. Self-organization on a nanometric scale occurs in solution due to the irreversible Si–O–Si bond formation that brings the organic units close to each other, favoring supramolecular van der Waals type interactions by decreasing the entropy. Micrometric scale organization takes place during ageing in the solid state. Densification of the Si–O–Si framework and reorganization of the micrometric aggregates generates stresses that are released by the formation of cracks that lead, upon propagation, to a birefringence phenomenon." @default.
- W2038638071 created "2016-06-24" @default.
- W2038638071 creator A5051623571 @default.
- W2038638071 creator A5078163332 @default.
- W2038638071 creator A5086822968 @default.
- W2038638071 date "2006-01-01" @default.
- W2038638071 modified "2023-10-17" @default.
- W2038638071 title "Supramolecular self-organization in non-crystalline hybrid organic–inorganic nanomaterials induced by van der Waals interactions" @default.
- W2038638071 cites W17355806 @default.
- W2038638071 cites W1908492443 @default.
- W2038638071 cites W1941617184 @default.
- W2038638071 cites W1964683225 @default.
- W2038638071 cites W1975526697 @default.
- W2038638071 cites W197688159 @default.
- W2038638071 cites W1977791171 @default.
- W2038638071 cites W1985505596 @default.
- W2038638071 cites W1985928764 @default.
- W2038638071 cites W1987560557 @default.
- W2038638071 cites W1988738064 @default.
- W2038638071 cites W1988830315 @default.
- W2038638071 cites W1995973830 @default.
- W2038638071 cites W1996105465 @default.
- W2038638071 cites W1997112710 @default.
- W2038638071 cites W1999480345 @default.
- W2038638071 cites W2003118404 @default.
- W2038638071 cites W2008070802 @default.
- W2038638071 cites W2009829629 @default.
- W2038638071 cites W2011148278 @default.
- W2038638071 cites W2011231218 @default.
- W2038638071 cites W2017690254 @default.
- W2038638071 cites W2018485140 @default.
- W2038638071 cites W2019643182 @default.
- W2038638071 cites W2020246606 @default.
- W2038638071 cites W2025572131 @default.
- W2038638071 cites W2026466743 @default.
- W2038638071 cites W2028473966 @default.
- W2038638071 cites W2031415815 @default.
- W2038638071 cites W2033003534 @default.
- W2038638071 cites W2034969239 @default.
- W2038638071 cites W2035609599 @default.
- W2038638071 cites W2037368513 @default.
- W2038638071 cites W2037861733 @default.
- W2038638071 cites W2039025104 @default.
- W2038638071 cites W2039405963 @default.
- W2038638071 cites W2040221048 @default.
- W2038638071 cites W2040347199 @default.
- W2038638071 cites W2040416641 @default.
- W2038638071 cites W2043109355 @default.
- W2038638071 cites W2045550869 @default.
- W2038638071 cites W2047217537 @default.
- W2038638071 cites W2047386436 @default.
- W2038638071 cites W2049610885 @default.
- W2038638071 cites W2051109465 @default.
- W2038638071 cites W2051260051 @default.
- W2038638071 cites W2054024538 @default.
- W2038638071 cites W2057206468 @default.
- W2038638071 cites W2057786636 @default.
- W2038638071 cites W2058268700 @default.
- W2038638071 cites W2058698971 @default.
- W2038638071 cites W2059637064 @default.
- W2038638071 cites W2060445243 @default.
- W2038638071 cites W2060820767 @default.
- W2038638071 cites W2060983996 @default.
- W2038638071 cites W2067362013 @default.
- W2038638071 cites W2067799943 @default.
- W2038638071 cites W2069457721 @default.
- W2038638071 cites W2070189005 @default.
- W2038638071 cites W2071557025 @default.
- W2038638071 cites W2076243473 @default.
- W2038638071 cites W2077326302 @default.
- W2038638071 cites W2080120620 @default.
- W2038638071 cites W2085291956 @default.
- W2038638071 cites W2085657021 @default.
- W2038638071 cites W2085868290 @default.
- W2038638071 cites W2085974754 @default.
- W2038638071 cites W2093363158 @default.
- W2038638071 cites W2093988152 @default.
- W2038638071 cites W2103912606 @default.
- W2038638071 cites W2121528824 @default.
- W2038638071 cites W2121821565 @default.
- W2038638071 cites W2123015115 @default.
- W2038638071 cites W2137265130 @default.
- W2038638071 cites W2137480479 @default.
- W2038638071 cites W2144283342 @default.
- W2038638071 cites W2158645343 @default.
- W2038638071 cites W2168506832 @default.
- W2038638071 cites W2951263006 @default.
- W2038638071 cites W2952286113 @default.
- W2038638071 cites W2953203145 @default.
- W2038638071 doi "https://doi.org/10.1039/b603655d" @default.
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