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- W2038642376 abstract "Abstract Pentakis(trimethylsilyl)-3-phospha-2-pentazene (Me3Si)2N-N(SiMe3)-P = N-N(SiMe3)2 (1) reacts with AlCl3 and TiCl4 (MXn) to form an iminophosphorane, (Me3Si)2N-N(SiMe3)-P(X)(MXn-1) = N-N(SiMe3)2. The latter decomposes to form 3,5,5-trichloro-1,2-bis(trimethylsilyl)-4-bis(trimethylsilyl)amino-1,2-diaza-3-phospha-4-amino-5-titanacyclo-pentane. SbCl3, forms a similar cyclic product 3,5-dichloro-l,2-bis (trimethylsilyl)-4-bis(trimethylsilyl)amino-l,2-diaza-3-phospha-4-amino-5-stibacyclopentane. Lewis acids SnCl4 and SbCl5 act as oxidants to yield Me3Si-N = N-P = N-N(SiMe3)2." @default.
- W2038642376 created "2016-06-24" @default.
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- W2038642376 date "1997-12-01" @default.
- W2038642376 modified "2023-09-28" @default.
- W2038642376 title "SILYL NITROGEN COMPOUNDS[1], V: REACTIONS OF PENTASILA-PHOSPHA-PENTAZENE WITH METAL CHLORIDES" @default.
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- W2038642376 doi "https://doi.org/10.1080/10426509708031610" @default.
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