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• W2038648632 endingPage "11811" @default.
• W2038648632 startingPage "11800" @default.
• W2038648632 abstract "Abstract This work describes the synthesis and full characterization of a series of GaCl 3 and B(C 6 F 5 ) 3 adducts of diazenes R 1 NNR 2 (R 1 =R 2 =Me 3 Si, Ph; R 1 =Me 3 Si, R 2 =Ph). Trans ‐PhNNPh forms a stable adduct with GaCl 3 , whereas no adduct, but instead a frustrated Lewis acid–base pair is formed with B(C 6 F 5 ) 3 . The cis ‐PhNNPh ⋅ B(C 6 F 5 ) 3 adduct could only be isolated when UV light was used, which triggers the isomerization from trans ‐ to cis ‐PhNNPh, which provides more space for the bulky borane. Treatment of trans ‐PhNNSiMe 3 with GaCl 3 led to the expected trans ‐PhNNSiMe 3 ⋅ GaCl 3 adduct but the reaction with B(C 6 F 5 ) 3 triggered a 1,2‐Me 3 Si shift, which resulted in the formation of a highly labile iso ‐diazene, Me 3 Si(Ph)NN; stabilized as a B(C 6 F 5 ) 3 adduct. Trans ‐Me 3 SiNNSiMe 3 forms a labile cis ‐Me 3 SiNNSiMe 3 ⋅ B(C 6 F 5 ) 3 adduct, which isomerizes to give the transient iso ‐diazene species (Me 3 Si) 2 NN ⋅ B(C 6 F 5 ) 3 upon heating. Both iso ‐diazene species insert easily into one BC bond of B(C 6 F 5 ) 3 to afford hydrazinoboranes. All new compounds were fully characterized by means of X‐ray crystallography, vibrational spectroscopy, CHN analysis, and NMR spectroscopy. All compounds were further investigated by DFT and the bonding situation was assessed by natural bond orbital (NBO) analysis." @default.
• W2038648632 created "2016-06-24" @default.
• W2038648632 creator A5047427644 @default.
• W2038648632 creator A5056409940 @default.
• W2038648632 creator A5059791629 @default.
• W2038648632 date "2014-07-24" @default.
• W2038648632 modified "2023-10-18" @default.
• W2038648632 title "Synthesis, Structure, and Reactivity of Diazene Adducts: Isolation of<i>iso</i>-Diazene Stabilized as a Borane Adduct" @default.
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