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- W2038702239 endingPage "1431" @default.
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- W2038702239 abstract "The reaction of the Bispyridyl Isoindole (BPI) type ligands L1 and L2 (L1 = 1,3-Bis(2-(4-tert-butylpyridyl)imino) isoindole, L2 = 1,3-Bis(2-(5-bromo)imino)-5,6-dimethylisoindole) with [Ru(μ-Cl)2(cod)]x in presence of triethylamine using coordinating solvents like acetonitrile, dimethyl sulfoxide or pyridine cleanly gave the complexes [{BPI(L1,L2)}RuII(Cl)(S)2] (L1: S = acetonitrile (1), dimethyl sulfoxide (2), pyridine (3); L2: S = acetonitrile (4), dimethyl sulfoxide (5), pyridine (6)). In these complexes the BPI ligands meridionally coordinated to the ruthenium center as established by X-ray diffraction for complexes 3 and 6. The catalytic activity in the direct ATRP (Atom Transfer Radical Polymerization) of styrene was tested for complexes 1–6." @default.
- W2038702239 created "2016-06-24" @default.
- W2038702239 creator A5047158086 @default.
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- W2038702239 date "2011-04-01" @default.
- W2038702239 modified "2023-10-09" @default.
- W2038702239 title "Synthesis and structural chemistry of bis(pyridylimino)isoindolato–ruthenium complexes and their activity as mediators in the atom transfer radical polymerization (ATRP) of styrene" @default.
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- W2038702239 doi "https://doi.org/10.1016/j.jorganchem.2011.01.009" @default.
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