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- W2038703670 abstract "Cycloheptatrienemolybdenum tricarbonyl reacted with ligands (L) (L = phenyl-, o -tolyl-, m -tolyl-, p -tolyl-, α-naphthyl-, β-naphthyl-, sym -diphenyl-, sym -di- o -tolyl-, sym -di- p -tolyl, or sym -di-α-naphthyl-thiourea) to give Mo(CO) 5 L derivatives although the expected products were cis -Mo(CO) 3 L 3 . Evidence has been obtained for the formation of trans -Mo(CO) 4 L 2 derivatives when L = sym -diphenyl- and sym -di- o -tolyl-thiourea. These donors on reaction with Mo(CO) 4 B (B = o -phenanthroline or 2,2′-bipyridine) yielded mixed ligand derivatives of the type Mo(CO) 3 BL. The appearance of three CO stretching bands is in agreement with the C s symmetry of mixed-ligand molybdenum carbonyls." @default.
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- W2038703670 date "1976-04-01" @default.
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- W2038703670 title "Reactions of aryl- and diaryl-thioureas with some molybdenum carbonyl derivatives" @default.
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- W2038703670 doi "https://doi.org/10.1016/s0022-328x(00)90159-1" @default.
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