Matches in SemOpenAlex for { <https://semopenalex.org/work/W2038741805> ?p ?o ?g. }
- W2038741805 abstract "studied substrate of 1,2-phenylene phosphorochloridate is cyclic five-membered ring of phosphorus ester, and the anilinolysis rate of 1 is much faster than its acyclic analogue (4: ethyl phenyl chlorophosphate) because of extremely small magnitude of the entropy of activation of 1 compared to 4. The Hammett and Bronsted plots exhibit biphasic concave upwards for substituent X variations in the nucleophiles with a break point at X = 3Me. The values of deuterium kinetic isotope effects (DKIEs; kH/kD) change from secondary inverse (kH/kD 1) with the weakly basic anilines. The secondary inverse with the strongly basic anilines and primary normal DKIEs with the weakly basic anilines are rationalized by the transition state (TS) variation from a predominant backside attack to a predominant frontside attack, in which the reaction mechanism is a concerted SN2 pathway. The primary normal DKIEs are substantiated by a hydrogen bonded, four-center-type TS." @default.
- W2038741805 created "2016-06-24" @default.
- W2038741805 creator A5011060919 @default.
- W2038741805 creator A5065599650 @default.
- W2038741805 date "2011-09-20" @default.
- W2038741805 modified "2023-09-30" @default.
- W2038741805 title "Kinetics and Mechanism of the Anilinolysis of 1,2-Phenylene Phosphorochloridate in Acetonitrile" @default.
- W2038741805 cites W119856943 @default.
- W2038741805 cites W1440533077 @default.
- W2038741805 cites W1544623992 @default.
- W2038741805 cites W1607104652 @default.
- W2038741805 cites W1643059092 @default.
- W2038741805 cites W1967018847 @default.
- W2038741805 cites W1968048028 @default.
- W2038741805 cites W1968429058 @default.
- W2038741805 cites W1970789261 @default.
- W2038741805 cites W1982159122 @default.
- W2038741805 cites W1982248385 @default.
- W2038741805 cites W1982408286 @default.
- W2038741805 cites W1988046726 @default.
- W2038741805 cites W1996831585 @default.
- W2038741805 cites W2001380180 @default.
- W2038741805 cites W2008841323 @default.
- W2038741805 cites W2009085670 @default.
- W2038741805 cites W2013342240 @default.
- W2038741805 cites W2015503021 @default.
- W2038741805 cites W2021015458 @default.
- W2038741805 cites W2021142922 @default.
- W2038741805 cites W2022892635 @default.
- W2038741805 cites W2024866863 @default.
- W2038741805 cites W2030286780 @default.
- W2038741805 cites W2035898297 @default.
- W2038741805 cites W2041342813 @default.
- W2038741805 cites W2041663448 @default.
- W2038741805 cites W2046325850 @default.
- W2038741805 cites W2046833224 @default.
- W2038741805 cites W2052870942 @default.
- W2038741805 cites W2053127377 @default.
- W2038741805 cites W2058367104 @default.
- W2038741805 cites W2058550017 @default.
- W2038741805 cites W2061335665 @default.
- W2038741805 cites W2064262385 @default.
- W2038741805 cites W2065746912 @default.
- W2038741805 cites W2066234059 @default.
- W2038741805 cites W2070023411 @default.
- W2038741805 cites W2071289797 @default.
- W2038741805 cites W2071313364 @default.
- W2038741805 cites W2073923208 @default.
- W2038741805 cites W2074029195 @default.
- W2038741805 cites W2076233914 @default.
- W2038741805 cites W2077018811 @default.
- W2038741805 cites W2079453432 @default.
- W2038741805 cites W2087571225 @default.
- W2038741805 cites W2093700302 @default.
- W2038741805 cites W2105875448 @default.
- W2038741805 cites W2122803878 @default.
- W2038741805 cites W2127307145 @default.
- W2038741805 cites W2131283189 @default.
- W2038741805 cites W2147301390 @default.
- W2038741805 cites W2156428107 @default.
- W2038741805 cites W2160790360 @default.
- W2038741805 cites W2169692907 @default.
- W2038741805 cites W2317582368 @default.
- W2038741805 cites W2327865522 @default.
- W2038741805 cites W239119187 @default.
- W2038741805 cites W25635351 @default.
- W2038741805 cites W2951495268 @default.
- W2038741805 cites W2952043064 @default.
- W2038741805 cites W388659523 @default.
- W2038741805 cites W417688916 @default.
- W2038741805 cites W595673949 @default.
- W2038741805 doi "https://doi.org/10.5012/bkcs.2011.32.9.3355" @default.
- W2038741805 hasPublicationYear "2011" @default.
- W2038741805 type Work @default.
- W2038741805 sameAs 2038741805 @default.
- W2038741805 citedByCount "13" @default.
- W2038741805 countsByYear W20387418052012 @default.
- W2038741805 countsByYear W20387418052017 @default.
- W2038741805 crossrefType "journal-article" @default.
- W2038741805 hasAuthorship W2038741805A5011060919 @default.
- W2038741805 hasAuthorship W2038741805A5065599650 @default.
- W2038741805 hasBestOaLocation W20387418051 @default.
- W2038741805 hasConcept C121332964 @default.
- W2038741805 hasConcept C148898269 @default.
- W2038741805 hasConcept C155647269 @default.
- W2038741805 hasConcept C161790260 @default.
- W2038741805 hasConcept C178790620 @default.
- W2038741805 hasConcept C178907741 @default.
- W2038741805 hasConcept C185592680 @default.
- W2038741805 hasConcept C2776026683 @default.
- W2038741805 hasConcept C2777463227 @default.
- W2038741805 hasConcept C2778689049 @default.
- W2038741805 hasConcept C521977710 @default.
- W2038741805 hasConcept C58364064 @default.
- W2038741805 hasConcept C62520636 @default.
- W2038741805 hasConcept C69928629 @default.
- W2038741805 hasConcept C71240020 @default.
- W2038741805 hasConcept C96765332 @default.
- W2038741805 hasConceptScore W2038741805C121332964 @default.
- W2038741805 hasConceptScore W2038741805C148898269 @default.