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• W2038743556 endingPage "3626" @default.
• W2038743556 startingPage "3618" @default.
• W2038743556 abstract "In the gas phase at room temperature, the coordination process of NH3, C2H4, CF4, SF6, and Xe onto “naked” W(CO)5, selectively prepared by pulsed 355-nm laser photolysis of W(CO)6, was investigated by laser-based time-resolved infrared absorption spectroscopy. W(CO)5 reacted with these reactant gases, except for CF 4 and SF6, to make a simple coordination complex, W(CO)5(L), where L is NH3, C2H4, or Xe. The bimolecular rate constants for these reactions were (5.6 ± 0.6) × 106 Torr−1 s−1 for W(CO)5 + NH3, (2.8 ± 0.5) × 106 Torr−1 s−1 for W(CO)5 + C2H4, and (1.0 ± 0.3) × 105 Torr−1 s−1 for W(CO)5 + Xe. W(CO)5Xe was unstable owing to its weak interaction with the coordinatively unsaturated tungsten center, the unimolecular decomposition rate of which was about 1.0 × 105 s−1, but W(CO)5(NH3) and W(CO)5(η2-C2H4) were stable under our experimental conditions. The band shifts of C–O stretching modes observed in the coordination of NH3 as a typical σ-donor, C2H4 as a typical π-acceptor, and Xe as a weak σ-donor could interpreted by MO considerations." @default.
• W2038743556 created "2016-06-24" @default.
• W2038743556 creator A5015483676 @default.
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• W2038743556 creator A5083779363 @default.
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• W2038743556 date "1993-12-01" @default.
• W2038743556 modified "2023-09-24" @default.
• W2038743556 title "Coordination of Some Simple Molecules onto W(CO)₅in the Gas Phase" @default.
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• W2038743556 doi "https://doi.org/10.1246/bcsj.66.3618" @default.
• W2038743556 hasPublicationYear "1993" @default.
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