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- W2038751876 abstract "Unerwartete Ligandenanordungen für fünffach koordinierte d°‐Metallkomplexe sind das Ergebnis theoretischer und experimenteller Studien. Ab‐initio‐Rechnungen an [TaH 5 ] und [Ta(CH) 3 ] 1 zeigen, daß in beiden Fällen die quadratisch‐pyramidale Koordination gegenüber der üblichen trigonal‐bipramidalen bevorzugt ist, was im Falle des Pentamethylkomplexes durch Elektronenbeugung in der Gasphase betätigt wurde. Die Hauptgruppenelement‐Verbindung [Sb(CH 3 ) 5 ] 2 ist dagegen trigonal‐bipyramidal gebaut, aber nur durch eine kleine Energiebarriere von der quadratisch‐pyramidalen Form getrennt. magnified image" @default.
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- W2038751876 date "1992-11-01" @default.
- W2038751876 modified "2023-10-10" @default.
- W2038751876 title "Die Strukturen von Pentamethyltantal und Pentamethylantimon: eine quadratische Pyramide bzw. eine trigonale Bipyramide" @default.
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- W2038751876 doi "https://doi.org/10.1002/ange.19921041130" @default.
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