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- W2038773701 abstract "Die strahlenchemische Oxydation millimolarer sauerstoffhaltiger Lösungen von Schwefeldioxid in 2 bis 16 m Schwefelsäure wurde unter Röntgenbestrahlung (65, 140 und 190 kV) im Dosisleistungsbereich von 0,14 bis 6,6 · 1015 eV · ml−1 · s−1 untersucht. Auf der Grundlage früherer Veröffentlichungen wird aus der Abhängigkeit der strahlenchemischen Ausbeute von Schwefelsäurekonzentration und Dosisleistung ein Mechanismus abgeleitet, nach dem die Reaktion über das instabile Peroxohydrogensulfitradikal HOOSO2. abläuft. The Effect of Ionizing Radiation on the System SO2O2. VII. Radiation-induced Oxidation of Sulfur Dioxide Dissolved in Sulfuric Acid The radiation-induced oxidation of oxygen-containing millimolar solutions of sulfur dioxide in 2 to 16 M sulfuric acid was investigated under influence of X-rays (65, 140 and 190kV) with dose rates ranging from 0.14 to 6.6 · 1015 eV · ml−1 · s−1. On the basis of previous publications a mechanism is derived from the dependence of radiation-chemical yield upon concentration of sulfuric acid and dose rate which proceeds with the HOOSO2 · radical as an instable intermediate." @default.
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- W2038773701 date "1978-02-01" @default.
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- W2038773701 title "Die Einwirkung ionisierender Strahlen auf das System Schwefeldioxid ? Sauerstoff. VII. Untersuchungen �ber die Strahlenchemische Oxydation von Schwefeldioxid in schwefelsaurer L�sung" @default.
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- W2038773701 doi "https://doi.org/10.1002/zaac.19784380130" @default.
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