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• W2038803003 abstract "The (cyclopentadienyl)(carbonyl)oligoselenidotungsten(II) complexes [cp(CO)3W]2Sen, n = 2, 3, and 4, have been prepared by insertion of selenium into the lithium−tungsten bond of LiWcp(CO)3 in different ratios and oxidation with silica gel in THF. NMR studies reveal different conformations of the cyclopentadienyl ligands in solution. The crystal structure of [cpW(CO)3]2Se3 is reported. The Se3 group acts as a bridging ligand in a μ2−η1 mode with Se−Se bond lengths of 2.342(2) and 2.348(2) Å and W−Se bond lengths of 2.632(1) and 2.651(1) Å." @default.
• W2038803003 created "2016-06-24" @default.
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• W2038803003 date "1996-01-01" @default.
• W2038803003 modified "2023-10-16" @default.
• W2038803003 title "Organometallic Selenolates. 3.¹ Oxidation of (Cyclopentadienyl)tungsten Selenolates and Crystal Structure of [(cp)W(CO)₃]₂Se₃" @default.
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• W2038803003 doi "https://doi.org/10.1021/ic951394b" @default.
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