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- W2038812955 abstract "Abstract The reactions of tin tetrachloride and four terminal alkynes (PhC CH, tBuC CH, nBuC CH, HOCH2C CH), norbornene, and norbornadiene in dichloromethane or chloroform solution lead to the formation of stannylation products, which were characterized by 1H, 13C and 119Sn NMR spectroscopy. Virtually complete α-regioselectivity was obtained in reaction of all four alkynes without any effect of the relative steric bulk of the substituent R at the triple bond of alkyne RCβ CαH. The reaction of norbornene and norbornadiene with SnCl4 is stereoselective, giving an exo stannylation product." @default.
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- W2038812955 date "2011-09-01" @default.
- W2038812955 modified "2023-10-08" @default.
- W2038812955 title "Stannylation of unsaturated carbon–carbon bonds by tin tetrachloride" @default.
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- W2038812955 doi "https://doi.org/10.1016/j.jorganchem.2011.06.002" @default.
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